Practical Conversion of Chlorosilanes into Alkoxysilanes without Generating HCl†
Ryutaro Wakabayashi
Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan) http://www.waseda.jp/sem-kuroda_lab/
Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo, 169-0051 (Japan)
Search for more papers by this authorYasushi Sugiura
Dow Corning Toray Co., Ltd. Chigusa-Kaigan-2, Ichihara-shi, Chiba 299-0108 (Japan)
Search for more papers by this authorDr. Toshimichi Shibue
Materials Characterization Central Laboratory, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Kazuyuki Kuroda
Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan) http://www.waseda.jp/sem-kuroda_lab/
Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo, 169-0051 (Japan)
Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan) http://www.waseda.jp/sem-kuroda_lab/Search for more papers by this authorRyutaro Wakabayashi
Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan) http://www.waseda.jp/sem-kuroda_lab/
Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo, 169-0051 (Japan)
Search for more papers by this authorYasushi Sugiura
Dow Corning Toray Co., Ltd. Chigusa-Kaigan-2, Ichihara-shi, Chiba 299-0108 (Japan)
Search for more papers by this authorDr. Toshimichi Shibue
Materials Characterization Central Laboratory, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Kazuyuki Kuroda
Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan) http://www.waseda.jp/sem-kuroda_lab/
Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo, 169-0051 (Japan)
Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555 (Japan) http://www.waseda.jp/sem-kuroda_lab/Search for more papers by this authorThe authors are grateful to Dr. S. Sueki, Mr. K. Kawahara, Mr. H. Tachibana, and Ms. M. Tamai (Waseda University) for helpful discussions. This work was supported in part by a Grant-in-Aid for Scientific Research (No. 23245044) and the Global COE program “Practical Chemical Wisdom” from the MEXT (Japan). K.K. also acknowledges the support by Elements Science and Technology Project “Functional Designs of Silicon-Oxygen-Based Compounds by Precise Synthetic Strategies” from the MEXT (Japan).
Graphical Abstract
Alkoholfrei: Eine vielseitige und effiziente Synthese von Alkoxysilanen ohne Bildung von HCl gelingt durch die Reaktion von Chlorsilanen mit unsymmetrischen Ethern in Gegenwart einer Lewis-Säure (siehe Schema). Dieser verbesserte praktische Prozess beruht auf der selektiven Spaltung einer C-O-Bindung. Industriell einsetzbare Reagentien werden verwendet, und es entsteht nur ein einziges Koppelprodukt.
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