A Formal High Oxidation State Inverse-Sandwich Diuranium Complex: A New Route to f-Block-Metal Bonds†
Dr. Dipti Patel
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorDr. Fabrizio Moro
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorDr. Jonathan McMaster
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorDr. William Lewis
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorProf. Alexander J. Blake
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorCorresponding Author
Dr. Stephen T. Liddle
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorDr. Dipti Patel
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorDr. Fabrizio Moro
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorDr. Jonathan McMaster
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorDr. William Lewis
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorProf. Alexander J. Blake
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
Search for more papers by this authorCorresponding Author
Dr. Stephen T. Liddle
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)Search for more papers by this authorWe thank the Royal Society, the EPSRC, the ERC, the University of Nottingham, and the UK National Nuclear Laboratory for supporting this work and Prof. Dr. Joris van Slageren (University of Stuttgart) for discussions about the magnetism of 3.
Graphical Abstract
Uran-Cobalt-Bindung: Reduktion von [U(TsXy)(Cl)(thf)] [TsXy=HC(SiMe2NAr)3; Ar=3,5-Me2C6H3] mit KC8 in Toluol lieferte den Aren-verbrückten Diurankomplex 1, während in aliphatischen Kohlenwasserstoffen eine C-N-Aktivierung unter Bildung eines Imidoarylkomplexes stattfand, der ungewöhnliche ferromagnetische Wechselwirkungen zwischen den Uranzentren zeigt. Der präparative Nutzen von 1 wurde in der ersten Synthese eines U-Co-Komplexes, [U(TsXy)Co(CO)3(PPh3)] (2), gezeigt.
Supporting Information
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