Tuning the Spin State of Cobalt in a Co–La Heterometallic Complex through Controllable Coordination Sphere of La†
Dr. Song-Song Bao
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Search for more papers by this authorDr. Yi Liao
Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorDr. Yan-Hui Su
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Search for more papers by this authorXu Liang
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Search for more papers by this authorDr. Feng-Chun Hu
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Search for more papers by this authorDr. Zhihu Sun
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Li-Min Zheng
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Li-Min Zheng, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Shiqiang Wei, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Jing Ma, Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shiqiang Wei
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Li-Min Zheng, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Shiqiang Wei, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Jing Ma, Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorProf. Dr. Roger Alberto
Institute of Inorganic Chemistry, University of Zurich, 8057 Zurich (Switzerland)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jing Ma
Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Li-Min Zheng, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Shiqiang Wei, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Jing Ma, Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorDr. Song-Song Bao
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Search for more papers by this authorDr. Yi Liao
Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorDr. Yan-Hui Su
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Search for more papers by this authorXu Liang
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Search for more papers by this authorDr. Feng-Chun Hu
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Search for more papers by this authorDr. Zhihu Sun
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Li-Min Zheng
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Li-Min Zheng, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Shiqiang Wei, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Jing Ma, Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shiqiang Wei
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Li-Min Zheng, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Shiqiang Wei, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Jing Ma, Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorProf. Dr. Roger Alberto
Institute of Inorganic Chemistry, University of Zurich, 8057 Zurich (Switzerland)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jing Ma
Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Li-Min Zheng, State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China), Fax: (+86) 25-8331-4502
Shiqiang Wei, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (P. R. China)
Jing Ma, Theoretical and Computational Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (P. R. China)
Search for more papers by this authorFinancial supports by the NSF of China (No. 11079021, 20825312, 10725522, 21021062), NSF of Jiangsu Province (No. BK2009009), the National Basic Research Program of China (2007CB925102, 2010CB923402, 2011CB808600) are acknowledged. We thank Prof. N. Kobayashi for valuable discussions.
Graphical Abstract
Die reversible Dehydratisierung von Komplex 1 schaltet den Spinzustand des Cobalts von Low-Spin(LS)-CoIII zu High-Spin(HS)-CoII (siehe Bild). Dies ermöglicht es, das magnetische Moment von 0.48 μB bei 120 °C auf 4.15 μB bei 220 °C im vollständig dehydratisierten Komplex 1-220 hochzufahren. notpH6=1,4,7-Triazacyclononan-1,4,7-triyltris(methylenphosphonsäure).
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