Where is the Heavy-Atom Effect? Role of the Central Ligand in Tetragold(I) Ethynyl Complexes†
Corresponding Author
Dr. Glenna So Ming Tong
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, and
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, andSearch for more papers by this authorPui Keong Chow
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, and
Search for more papers by this authorCorresponding Author
Prof. Dr. Chi-Ming Che
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, and
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, andSearch for more papers by this authorCorresponding Author
Dr. Glenna So Ming Tong
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, and
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, andSearch for more papers by this authorPui Keong Chow
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, and
Search for more papers by this authorCorresponding Author
Prof. Dr. Chi-Ming Che
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, and
State Key Laboratory on Synthetic Chemistry, Institute of Molecular Functional Materials, and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong (China), Fax: (+86) 852-2857-1586, andSearch for more papers by this authorWe would like to thank the University Development Fund and the AoE (Area of Excellence Scheme) Program of the University of Hong Kong (Project No. [AoE/P-03/08]) for financial support. We also thank the Computer Centre at the University of Hong Kong for providing supercomputers.
Graphical Abstract
Zentrale Bedeutung: Der Schweratom-Effekt bestimmt nicht als einziger Faktor die Effizienz des Intersystem-Crossings und die Geschwindigkeit des stahlenden Zerfalls von Triplettzuständen. Experimente und Rechnungen stellen die entscheidende Bedeutung des Brückenliganden für die Lumineszenzeigenschaften von Tetra(gold(I)-ethinyl)-Komplexen heraus (siehe Strukturen und Darstellungen der höchsten besetzten Molekülorbitale).
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