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Chemie der Boroxide: Der Kreis schließt sich^†

Corresponding Author

Prof. Stephen A. Westcott

[email protected]

Department of Chemistry and Biochemistry, Mount Allison University, 63C York Street, Sackville, NB E4L 1G8 (Kanada), Fax: (+1) 506-364-2372

Department of Chemistry and Biochemistry, Mount Allison University, 63C York Street, Sackville, NB E4L 1G8 (Kanada), Fax: (+1) 506-364-2372Search for more papers by this author

Prof. Stephen A. Westcott,

Corresponding Author

Prof. Stephen A. Westcott

[email protected]

Department of Chemistry and Biochemistry, Mount Allison University, 63C York Street, Sackville, NB E4L 1G8 (Kanada), Fax: (+1) 506-364-2372

Department of Chemistry and Biochemistry, Mount Allison University, 63C York Street, Sackville, NB E4L 1G8 (Kanada), Fax: (+1) 506-364-2372Search for more papers by this author

First published: 28 September 2010

https://doi.org/10.1002/ange.201003379

Citations: 7

^†

Ich danke dem Canada Research Chairs Programme, dem Canadian Foundation for Innovation–Atlantic Innovation Fund und dem Natural Science and Engineering Research Council of Canada für Unterstützung sowie Prof. Dr. Holger Braunschweig für hilfreiche Diskussionen.

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Graphical Abstract

Niederkoordinierte Borzentren können durch Verwendung später Übergangsmetalle, z. B. eines Platin-Bisphosphan-Fragments, stabilisiert werden. [Pt(PCy₃)₂] reagiert mit Br₂BOSiMe₃ zu trans-[(PCy₃)₂PtBr(BO)], das eine ungewöhnlich stabile BO-Bindung enthält (siehe Bild, Cy= Cyclohexyl).

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Volume122, Issue48

November 22, 2010

Pages 9229-9230

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Chemie der Boroxide: Der Kreis schließt sich^†

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Chemie der Boroxide: Der Kreis schließt sich^†