A Persistent α-Fluorocarbanion and Its Analogues: Preparation, Characterization, and Computational Study†
G. K. Surya Prakash Prof. Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorFang Wang
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorNan Shao
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorThomas Mathew Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorGolam Rasul Prof. Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorRalf Haiges Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorTimothy Stewart
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorGeorge A. Olah Prof. Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorG. K. Surya Prakash Prof. Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorFang Wang
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorNan Shao
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorThomas Mathew Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorGolam Rasul Prof. Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorRalf Haiges Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorTimothy Stewart
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorGeorge A. Olah Prof. Dr.
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA-90089-1661 (USA), Fax: (+1) 213-740-6679
Search for more papers by this authorSupport of our work by Loker Hydrocarbon Research Institute is gratefully acknowledged.
Abstract
Starkes Fluor: In Einklang mit theoretischen Studien zu α-Fluorcarbanionen ergab eine Röntgenstrukturanalyse für das α-Fluorbis(phenylsulfonyl)methid-Anion eine pyramidale Konfiguration (siehe Bild). Anspruchsvolle Rechnungen und NMR-spektroskopische Studien zeigten, dass elektronenziehende Substituenten die Eigenschaften von Bis(phenylsulfonyl)methid-Anionen entscheidend beeinflussen.
Supporting Information
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