Frustrated Phases of Block Copolymers in Nanoparticles
Takeshi Higuchi Dr.
WPI Research Center, Advanced Institute for Materials Research, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577 (Japan), Fax: (+81) 22-217-5329 http://poly.tagen.tohoku.ac.jp
Search for more papers by this authorAtsunori Tajima
Graduate School of Science, Hokaido University, Sapporo 060-0810 (Japan)
Search for more papers by this authorKiwamu Motoyoshi
Graduate School of Engineering, Tohoku University, Sendai 980-8577 (Japan)
Search for more papers by this authorHiroshi Yabu Prof. Dr.
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)
Search for more papers by this authorMasatsugu Shimomura Prof. Dr.
WPI Research Center, Advanced Institute for Materials Research, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577 (Japan), Fax: (+81) 22-217-5329 http://poly.tagen.tohoku.ac.jp
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)
Search for more papers by this authorTakeshi Higuchi Dr.
WPI Research Center, Advanced Institute for Materials Research, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577 (Japan), Fax: (+81) 22-217-5329 http://poly.tagen.tohoku.ac.jp
Search for more papers by this authorAtsunori Tajima
Graduate School of Science, Hokaido University, Sapporo 060-0810 (Japan)
Search for more papers by this authorKiwamu Motoyoshi
Graduate School of Engineering, Tohoku University, Sendai 980-8577 (Japan)
Search for more papers by this authorHiroshi Yabu Prof. Dr.
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)
Search for more papers by this authorMasatsugu Shimomura Prof. Dr.
WPI Research Center, Advanced Institute for Materials Research, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577 (Japan), Fax: (+81) 22-217-5329 http://poly.tagen.tohoku.ac.jp
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)
Search for more papers by this authorGraphical Abstract
Nanopartikuläre Blockcopolymere bilden neuartige phasengetrennte Formen, deren Entstehung auf einem strukturfrustrierenden Begrenzungseffekt der Partikel beruht. Während Filme des Blockcopolymers lamellare Strukturen einnehmen, bilden die Nanopartikel spezielle Morphologien (ball-, pilz-, rad- und schraubenförmige sowie Janus-Strukturen), je nach Verhältnis von Partikeldurchmesser und Molekulargewicht des Polymers.
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