Reactions of a Copper(II) Superoxo Complex Lead to CH and OH Substrate Oxygenation: Modeling Copper-Monooxygenase CH Hydroxylation†
Debabrata Maiti
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Search for more papers by this authorDong-Heon Lee Prof. Dr.
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Current addresses: Department of Chemistry and Research Institute of Physics and Chemistry (RINPAC), Chonbuk National University, Jeonju 561-756, Korea
Search for more papers by this authorKatya Gaoutchenova Dr.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany
Search for more papers by this authorChristian Würtele
Institut für Anorganische und Analytische Chemie, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, 35392 Gießen, Germany
Search for more papers by this authorMax C. Holthausen Prof. Dr.
Institut für Anorganische und Analytische Chemie, Johann Wolfgang Goethe-Universität Frankfurt, Max-von-Laue Strasse 7, 60438 Frankfurt am Main, Germany
Search for more papers by this authorAmy A. Narducci Sarjeant Dr.
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Search for more papers by this authorJörg Sundermeyer Prof. Dr.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany
Search for more papers by this authorSiegfried Schindler Prof. Dr.
Institut für Anorganische und Analytische Chemie, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, 35392 Gießen, Germany
Search for more papers by this authorKenneth D. Karlin Prof.
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Search for more papers by this authorDebabrata Maiti
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Search for more papers by this authorDong-Heon Lee Prof. Dr.
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Current addresses: Department of Chemistry and Research Institute of Physics and Chemistry (RINPAC), Chonbuk National University, Jeonju 561-756, Korea
Search for more papers by this authorKatya Gaoutchenova Dr.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany
Search for more papers by this authorChristian Würtele
Institut für Anorganische und Analytische Chemie, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, 35392 Gießen, Germany
Search for more papers by this authorMax C. Holthausen Prof. Dr.
Institut für Anorganische und Analytische Chemie, Johann Wolfgang Goethe-Universität Frankfurt, Max-von-Laue Strasse 7, 60438 Frankfurt am Main, Germany
Search for more papers by this authorAmy A. Narducci Sarjeant Dr.
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Search for more papers by this authorJörg Sundermeyer Prof. Dr.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany
Search for more papers by this authorSiegfried Schindler Prof. Dr.
Institut für Anorganische und Analytische Chemie, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, 35392 Gießen, Germany
Search for more papers by this authorKenneth D. Karlin Prof.
Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA, Fax: (+1) 410-516-7044
Search for more papers by this authorWe are grateful to the NIH (K.D.K., GM28962) and Deutsche Forschungsgemeinschaft (J.S., S.S., and M.C.H.) for research support.
Graphical Abstract
Der Donor macht den Unterschied: Der Disauerstoff-Ligand des einkernigen η1-Superoxo-Kupfer(II)-Komplexes 1 wird durch Wasserstoffatomdonoren aktiviert. Der resultierende Einschub eines O-Atoms aus der O2-Gruppe in die N-gebundene Methylgruppe des Chelatliganden führt zu dem Kupfer(II)-alkoxid 2. Ohne Zusatz des Donors ist die Superoxospezies 1 nicht in der Lage, die beobachtete Hydroxylierung einzugehen.
Supporting Information
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