[Re12CS17(CN)6]n− (n=6, 8): A Sulfido–Cyanide Rhenium Cluster with an Interstitial Carbon Atom†
Yuri V. Mironov Dr.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorNikolai G. Naumov Dr.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorSvetlana G. Kozlova Dr.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorSung-Jin Kim Prof.
Department of Chemistry, Ewha Womans University, Seoul 120-750, Korea, Fax: (+82) 2-3277-2384
Search for more papers by this authorVladimir E. Fedorov Prof.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorYuri V. Mironov Dr.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorNikolai G. Naumov Dr.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorSvetlana G. Kozlova Dr.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorSung-Jin Kim Prof.
Department of Chemistry, Ewha Womans University, Seoul 120-750, Korea, Fax: (+82) 2-3277-2384
Search for more papers by this authorVladimir E. Fedorov Prof.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev pr., 630090 Novosibirsk, Russia, Fax: (+7) 3833-309489
Search for more papers by this authorThis work was supported by the Russian Foundation for Basic Research (grants 05-03-08090 and 05-03-32123), the International Cooperation Research Program of the Ministry of Science & Technology of Korea (grant M60403000099-04A0100-02310), and the Division of Chemistry and Sciences on Materials of RAS (project No. 15 of Program 4.1). The authors are grateful to the Boreskov Institute of Catalysis SB RAS for an opportunity to use the ADF program.
Graphical Abstract
Die Cyanidcluster [Re12CS17(CN)6]n− (n=8 oder 6) könnten als Bausteine für polymere Materialien dienen. Sie entstehen aus ReS2 in geschmolzenem KCN bei 750 °C. Die Clustereinheit umfasst zwei {Re6}-Oktaeder, die durch drei μ2-S-Brücken und ein interstitielles μ6-C-Atom verbunden sind (siehe Bild).
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