Dihedral-Angle Modulation of meso–meso-Linked ZnII Diporphyrin through Diamine Coordination and Its Application to Reversible Switching of Excitation Energy Transfer†
Hideyuki Shinmori Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, and, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation, Sakyo-ku, Kyoto 606–8502, Japan, Fax: (+81) 75-753-3970
Search for more papers by this authorTae Kyu Ahn Dr.
Center for Ultrafast Optical Characteristics Control and, Department of Chemistry, Yonsei University, Seoul 120–749, Korea, Fax: (+82) 2-2123-2434
Search for more papers by this authorHyun Sun Cho Dr.
Center for Ultrafast Optical Characteristics Control and, Department of Chemistry, Yonsei University, Seoul 120–749, Korea, Fax: (+82) 2-2123-2434
Search for more papers by this authorDongho Kim Prof.
Center for Ultrafast Optical Characteristics Control and, Department of Chemistry, Yonsei University, Seoul 120–749, Korea, Fax: (+82) 2-2123-2434
Search for more papers by this authorNaoya Yoshida Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, and, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation, Sakyo-ku, Kyoto 606–8502, Japan, Fax: (+81) 75-753-3970
Search for more papers by this authorAtsuhiro Osuka Prof.
Department of Chemistry, Graduate School of Science, Kyoto University, and, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation, Sakyo-ku, Kyoto 606–8502, Japan, Fax: (+81) 75-753-3970
Search for more papers by this authorHideyuki Shinmori Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, and, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation, Sakyo-ku, Kyoto 606–8502, Japan, Fax: (+81) 75-753-3970
Search for more papers by this authorTae Kyu Ahn Dr.
Center for Ultrafast Optical Characteristics Control and, Department of Chemistry, Yonsei University, Seoul 120–749, Korea, Fax: (+82) 2-2123-2434
Search for more papers by this authorHyun Sun Cho Dr.
Center for Ultrafast Optical Characteristics Control and, Department of Chemistry, Yonsei University, Seoul 120–749, Korea, Fax: (+82) 2-2123-2434
Search for more papers by this authorDongho Kim Prof.
Center for Ultrafast Optical Characteristics Control and, Department of Chemistry, Yonsei University, Seoul 120–749, Korea, Fax: (+82) 2-2123-2434
Search for more papers by this authorNaoya Yoshida Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, and, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation, Sakyo-ku, Kyoto 606–8502, Japan, Fax: (+81) 75-753-3970
Search for more papers by this authorAtsuhiro Osuka Prof.
Department of Chemistry, Graduate School of Science, Kyoto University, and, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation, Sakyo-ku, Kyoto 606–8502, Japan, Fax: (+81) 75-753-3970
Search for more papers by this authorThe work at Yonsei University was financially supported by the Creative Research Initiatives Program of the Ministry of Science and Technology of Korea. N.Y. thanks the JSPS Research Fellowship for Young Scientists.
Graphical Abstract
Der Diederwinkel in meso-meso-verknüpften ZnII-Diporphyrinen wird durch verbrückende Koordination von 1,7-Diaminoheptan an beide Zinkzentren eingestellt (siehe Bild). Als Folge dieser mechanischen Einschränkung wird die Energie des S1-Zustands der Zinkdiporphyrin-Einheit abgesenkt, und die Richtung des Energietransfers im angeregten Zustand kehrt sich um; der Prozess kann durch Zugabe von Essigsäure rückgängig gemacht werden.
Supporting Information
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