Aufsatz
Hoch effiziente asymmetrische Katalyse durch doppelte Aktivierung von Nucleophil und Elektrophil
Jun-An Ma Dr.,
Dominique Cahard Dr.,
Jun-An Ma Dr.
UMR 6014 CNRS de L'IRCOF, Université de Rouen, 1 Rue Tesnière, 76821 Mont Saint Aignan Cedex, Frankreich, Fax: (+33) 2-3552-2971
Institute and State Key Laboratory of Elemento-Organic Chemistry, Universität Nankai, Tianjin 300071, China
Search for more papers by this authorDominique Cahard Dr.
UMR 6014 CNRS de L'IRCOF, Université de Rouen, 1 Rue Tesnière, 76821 Mont Saint Aignan Cedex, Frankreich, Fax: (+33) 2-3552-2971
Search for more papers by this authorJun-An Ma Dr.,
Dominique Cahard Dr.,
Jun-An Ma Dr.
UMR 6014 CNRS de L'IRCOF, Université de Rouen, 1 Rue Tesnière, 76821 Mont Saint Aignan Cedex, Frankreich, Fax: (+33) 2-3552-2971
Institute and State Key Laboratory of Elemento-Organic Chemistry, Universität Nankai, Tianjin 300071, China
Search for more papers by this authorDominique Cahard Dr.
UMR 6014 CNRS de L'IRCOF, Université de Rouen, 1 Rue Tesnière, 76821 Mont Saint Aignan Cedex, Frankreich, Fax: (+33) 2-3552-2971
Search for more papers by this authorAbstract
Die Entwicklung neuer Hochleistungs-Katalysatoren für asymmetrische Katalysereaktionen ist für die Organische Chemie von dauerhaftem Interesse. Eine aktuelle Methode bei der stereoselektiven Synthese ist die Verwendung einer Kombination von Lewis-Säure und Lewis-Base. Der Synergieeffekt durch die Aktivierung mithilfe von zwei oder mehr reaktiven Zentren führt zu hohen Reaktionsgeschwindigkeiten und zu einer hervorragenden Übertragung der stereochemischen Information. Obwohl durch die unerwünschte Reaktion der Lewis-Säure mit der Lewis-Base der Katalysator inaktiviert werden kann, wird das Konzept der doppelten Aktivierung mit großem Aufwand weiterentwickelt. Das Ziel ist die Herstellung biomimetischer Katalysesysteme auf der Grundlage enzymatischer Prozesse mit cokatalytischen Metallionen. Doppelt aktivierende Katalysatorsysteme erweitern die Zahl bereits bekannter Katalysatoren beträchtlich. Die effektivsten dieser Systeme werden in diesem Aufsatz erörtert und die Wirkungsmechanismen diskutiert.
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