Solar-Powered Gram-Scale Ammonia Production from Nitrate
Paulraj Gnanasekar
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorKarthik Peramaiah
KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorHuafan Zhang
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorIbrahim G. Alsayoud
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorAnand S. Subbiah
KAUST Photovoltaics Laboratory, KAUST Solar Center, Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorMaxime Babics
KAUST Photovoltaics Laboratory, KAUST Solar Center, Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorTien Khee Ng
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorQiaoqiang Gan
Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorCorresponding Author
Stefaan De Wolf
KAUST Photovoltaics Laboratory, KAUST Solar Center, Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
E-mail:[email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Kuo-Wei Huang
KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
E-mail:[email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Boon S. Ooi
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
E-mail:[email protected]; [email protected]; [email protected]
Search for more papers by this authorPaulraj Gnanasekar
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorKarthik Peramaiah
KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorHuafan Zhang
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorIbrahim G. Alsayoud
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorAnand S. Subbiah
KAUST Photovoltaics Laboratory, KAUST Solar Center, Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorMaxime Babics
KAUST Photovoltaics Laboratory, KAUST Solar Center, Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorTien Khee Ng
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorQiaoqiang Gan
Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Search for more papers by this authorCorresponding Author
Stefaan De Wolf
KAUST Photovoltaics Laboratory, KAUST Solar Center, Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
E-mail:[email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Kuo-Wei Huang
KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
Department of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
E-mail:[email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Boon S. Ooi
Photonics Laboratory, Computer, Electrical, and Mathematical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900 Saudi Arabia
E-mail:[email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
The photoelectrochemical (PEC) method has the potential to be an attractive route for converting and storing solar energy as chemical bonds. In this study, a maximum NH3 production yield of 1.01 g L−1 with a solar-to-ammonia conversion efficiency of 8.17% through the photovoltaic electrocatalytic (PV-EC) nitrate (NO3−) reduction reaction (NO3−RR) is achieved, using silicon heterojunction solar cell technology. Additionally, the effect of tuning the operation potential of the PV-EC system and its influence on product selectivity are systematically investigated. By using this unique external resistance tuning approach in the PV-EC system, ammonia production through nitrate reduction performance from 96 to 360 mg L−1 is enhanced, a four-fold increase. Furthermore, the NH3 is extracted as NH4Cl powder using acid stripping, which is essential for storing chemical energy. This work demonstrates the possibility of tuning product selectivity in PV-EC systems, with prospects toward pilot scale on value-added product synthesis.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| smll202404249-sup-0001-SuppMat.pdf2.6 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1J. N. Galloway, W. H. Schlesinger, H. Levy, A. Michaels, J. L. Schnoor, Global Biogeochem. Cycles 1995, 9, 235.
- 2P. M. Vitousek, R. W. Howarth, Biogeochemistry 1991, 13, 87.
- 3Y. Wu, K. K. Lu, L. H. Xu, J. Mater. Chem. A 2023, 11, 17392.
- 4S. Samatya, N. Kabay, Ü. Yüksel, M. Arda, M. Yüksel, React. Funct. Polym. 2006, 66, 1206.
- 5R. Epsztein, O. Nir, O. Lahav, M. Green, Chem. Eng. J. 2015, 279, 372.
- 6L. J. Banasiak, A. I. Schäfer, J. Membr. Sci. 2009, 334, 101.
- 7S. Li, D. Han, G. Jiang, Z. Han, H. Lu, J. Gao, X. Wang, Y. Wang, C. Geng, Z. Weng, Q. H. Yang, ACS Appl. Energy Mater. 2023, 6, 5067.
- 8L. Mi, Q. Huo, J. Cao, X. Chen, H. Yang, Q. Hu, C. He, Adv. Energy Mater. 2022, 12, 2202247.
- 9L. F. Greenlee, Nat. Energy 2020, 5, 557.
- 10K. Dong, Y. Yao, H. Li, H. Li, S. Sun, X. He, Y. Wang, Y. Luo, D. Zheng, Q. Liu, Q. Li, D. Ma, X. Sun, B. Tang, Nat. Synth. 2024, 3, 763.
- 11H. Zhang, H. Wang, X. Cao, M. Chen, Y. Liu, Y. Zhou, M. Huang, L. Xia, Y. Wang, T. Li, D. Zheng, Y. Luo, S. Sun, X. Zhao, X. Sun, Adv. Mater. 2024, 36, 2312746.
- 12J. Liang, Z. Li, L. Zhang, X. He, Y. Luo, D. Zheng, Y. Wang, T. Li, H. Yan, B. Ying, S. Sun, Q. Liu, M. S. Hamdy, B. Tang, X. Sun, Chem 2023, 9, 1768.
- 13M. A. Mushtaq, A. Kumar, W. Liu, Q. Ji, Y. Deng, G. Yasin, A. Saad, W. Raza, J. Zhao, S. Ajmal, Y. Wu, M. Ahmad, R. Lashari, Y. Wang, T. Li, S. Sun, D. Zheng, Y. Luo, X. Cai, X. Sun, Adv. Mater. 2024, 36, 2313086.
- 14C. Ampelli, D. Giusi, M. Miceli, T. Merdzhanova, V. Smirnov, U. Chime, O. Astakhov, A. J. Martín, F. L. P. Veenstra, F. A. G. Pineda, J. González-Cobos, M. García-Tecedor, S. Giménez, W. Jaegermann, G. Centi, J. Pérez-Ramírez, J. R. Galán-Mascarós, S. Perathoner, Energy Environ. Sci. 2023, 16, 1644.
- 15H. C. Fu, P. Varadhan, C. H. Lin, J. H. He, Nat. Commun. 2020, 11, 3930.
- 16J. D. Butson, A. Sharma, H. Chen, Y. Wang, Y. Lee, P. Varadhan, M. N. Tsampas, C. Zhao, A. Tricoli, H. H. Tan, C. Jagadish, S. Karuturi, Adv. Energy Mater. 2022, 12, 2102752.
- 17P. Gnanasekar, D. Periyanagounder, P. Varadhan, J. H. He, J. Kulandaivel, ACS Appl. Mater. Interfaces 2019, 11, 44179.
- 18S. E. Jun, J. K. Lee, H. W. Jang, Energy Adv. 2023, 2, 34.
- 19H. Zhao, Z.-Y. Yuan, H. Zhao, Z.-Y. Yuan, Adv. Energy Mater. 2023, 13, 2300254.
- 20J. W. Yang, Y. J. Ahn, D. K. Cho, J. Y. Kim, H. W. Jang, Inorg. Chem. Front. 2023, 10, 3781.
- 21W. Li, H. Wang, X. Jiang, J. Zhu, Z. Liu, X. Guo, C. Song, RSC Adv. 2018, 8, 7651.
- 22A. Grimm, A. Sainte-Marie, G. J. Kramer, M. Gazzani, M. Gazzani, Int. J. Hydrogen Energy 2022, 47, 11764.
- 23M. T. Winkler, C. R. Cox, D. G. Nocera, T. Buonassisi, Proc. Natl. Acad. Sci. USA 2013, 110, E1076.
- 24B. Tang, F.-X. Xiao, ACS Catal. 2022, 12, 9023.
- 25Gurudayal, J. Bullock, D. F. Srankó, C. M. Towle, Y. Lum, M. Hettick, M. C. Scott, A. Javey, J. Ager, Energy Environ. Sci. 2017, 10, 2222.
- 26H. Li, S. Lin, H. Li, Z. Wu, Q. Chen, L. Zhu, C. Li, X. Zhu, Y. Sun, Small Methods 2022, 6, 2101320.
- 27D. Jia, D. Jiang, Y. Zheng, H. Tan, X. Cao, F. Liu, L. Yue, Y. Sun, J. Liu, Nanoscale 2019, 11, 2812.
- 28Y. Wang, Z. Yin, G. Yan, Z. Wang, X. Li, H. Guo, J. Wang, Electrochem. Acta 2020, 336, 135734.
- 29M. Wang, X. Liu, Y. Sun, X. Wu, New J. Chem. 2022, 46, 18535.
- 30H. Liang, F. Meng, M. Cabáncabán-Acevedo, L. Li, A. Forticaux, L. Xiu, Z. Wang, S. Jin, Nano Lett. 2015, 15, 1421.
- 31H. Liang, J. Lin, H. Jia, S. Chen, J. Qi, J. Cao, T. Lin, W. Fei, J. Feng, J. Mater. Chem. A 2018, 6, 15040.
- 32C. S. Santos, R. D. de Oliveira, L. F. Q. P. Marchesi, C. A. Pessôa, Arabian J. Chem. 2020, 13, 3448.
- 33N. Ullah, A. Shah, M. Xie, H. U. Rasheed, J. Oluigbo, D. Jiang, Y. Xu, J. Xie, Int. J. Hydrogen Energy 2019, 44, 14770.
- 34D. S. Hall, D. J. Lockwood, C. Bock, B. R. MacDougall, Proc. R. Soc. A 2015, 471, 1.
10.1098/rspa.2014.0792 Google Scholar
- 35P. Gnanasekar, D. Periyanagounder, J. Kulandaivel, Nanoscale 2019, 11, 2439.
- 36P. Gnanasekar, K. S. Ranjith, P. Manivel, Y.-K. Han, J. Kulandaivel, ACS Appl Energy Mater 2020, 3, 6717.
- 37F. Y. Chen, Z. Y. Wu, S. Gupta, D. J. Rivera, S. V. Lambeets, S. Pecaut, J. Y. T. Kim, P. Zhu, Y. Z. Finfrock, D. M. Meira, G. King, G. Gao, W. Xu, D. A. Cullen, H. Zhou, Y. Han, D. E. Perea, C. L. Muhich, H. Wang, Nat. Nanotechnol. 2022, 17, 759.
- 38W. Yu, J. Yu, M. Huang, Y. Wang, Y. Wang, J. Li, H. Liu, W. Zhou, Energy Environ. Sci 2023, 16, 2991.
- 39Z. Fang, Z. Jin, S. Tang, P. Li, P. Wu, G. Yu, ACS Nano 2022, 16, 1072.
- 40W. Gao, K. Xie, J. Xie, X. Wang, H. Zhang, S. Chen, H. Wang, Z. Li, C. Li, J. Ch, Adv. Mater. 2023, 35, 2202952.
- 41Y. Wang, A. Dutta, A. Iarchuk, C. Sun, S. Vesztergom, P. Broekmann, ACS Catal. 2023, 8169.
- 42 Green hydrogen: The scaling challenge – pv magazine USA, https://pv-magazine-usa.com/2023/06/29/green-hydrogen-the-scaling-challenge (accessed: June, 2024).
- 43M. Tao, J. A. Azzolini, E. B. Stechel, K. E. Ayers, T. I. Valdez, J. Electrochem. Soc. 2022, 169, 1.
- 44T. Nguyen, Z. Abdin, T. Holm, W. Mérida, Energy Convers. Manage. 2019, 200, 112108.
- 45J. Li, Y. Zhang, C. Liu, L. Zheng, E. Petit, K. Qi, Y. Zhang, H. Wu, W. Wang, A. Tiberj, X. Wang, M. Chhowalla, L. Lajaunie, R. Yu, D. Voiry, Adv. Funct. Mater. 2022, 32, 2108316.
- 46X. Liu, X. Xu, F. Li, J. Xu, H. Ma, X. Sun, D. Wu, C. Zhang, X. Ren, Q. Wei, ACS Appl. Mater. Interfaces 2022, 14, 38843.
- 47W. He, J. Zhang, S. Dieckhöfer, S. Varhade, A. C. Brix, A. Lielpetere, S. Seisel, J. R. C. Junqueira, W. Schuhmann, Nat. Commun. 2022, 13, 1129.
- 48Y. Wang, L. Zhang, Y. Niu, D. Fang, J. Wang, Q. Su, C. Wang, Green Chem. 2021, 23, 7594.
- 49P. Shen, X. Li, Y. Luo, Y. Guo, X. Zhao, K. Chu, ACS Nano 2022, 16, 7915.
- 50K. Chu, Y. Luo, P. Shen, X. Li, Q. Li, Y. Guo, K. Chu, Y. Luo, P. Shen, X. Li, Q. Li, Y. Guo, Adv. Energy Mater. 2022, 12, 2103022.
- 51Z. Zhang, M. Ma, H. Wang, P. Yun, Sol. Energy 2022, 236, 687.
- 52S. Sikkanthar, S. Karthikeyan, S. Selvasekarapandian, D. Arunkumar, H. Nithya, K. Junichi, Ionics 2016, 22, 1085.
- 53J. Hussain, H. Jónsson, E. Skúlason, ACS Catal. 2018, 8, 5240.
- 54D. Ashby, Electr. Eng. 2012, 101, 25.
