Journal of Polymer Science Part A: Polymer Chemistry

Article

Structural characterization and gas-transport properties of brominated matrimid polyimide^† ^‡

Corresponding Author

Michael D. Guiver

[email protected]

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, CanadaSearch for more papers by this author

Gilles P. Robertson,

Gilles P. Robertson

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Search for more papers by this author

Ying Dai,

Ying Dai

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Search for more papers by this author

François Bilodeau,

François Bilodeau

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Search for more papers by this author

Yong Soo Kang,

Yong Soo Kang

Center for Facilitated Transport Membranes and Polymer Physics Lab, Korea Institute of Science and Technology, P. O. Box 131, Cheongryang, Seoul 130-650, Korea

Search for more papers by this author

Kwi Jong Lee,

Kwi Jong Lee

Hyperstructured Organic Materials Research Center and School of Chemical Engineering, Seoul National University, Seoul 151-744, Korea

Search for more papers by this author

Jae Young Jho,

Jae Young Jho

Hyperstructured Organic Materials Research Center and School of Chemical Engineering, Seoul National University, Seoul 151-744, Korea

Search for more papers by this author

Jongok Won,

Jongok Won

Department of Applied Chemistry, Sejong University, Seoul 143-747, Korea

Search for more papers by this author

Michael D. Guiver,

Corresponding Author

Michael D. Guiver

[email protected]

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, CanadaSearch for more papers by this author

Gilles P. Robertson,

Gilles P. Robertson

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Search for more papers by this author

Ying Dai,

Ying Dai

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Search for more papers by this author

François Bilodeau,

François Bilodeau

Institute for Chemical Process and Environmental Technology, National Research Council of Canada, Ottawa, Ontario, K1A 0R6, Canada

Search for more papers by this author

Yong Soo Kang,

Yong Soo Kang

Center for Facilitated Transport Membranes and Polymer Physics Lab, Korea Institute of Science and Technology, P. O. Box 131, Cheongryang, Seoul 130-650, Korea

Search for more papers by this author

Kwi Jong Lee,

Kwi Jong Lee

Hyperstructured Organic Materials Research Center and School of Chemical Engineering, Seoul National University, Seoul 151-744, Korea

Search for more papers by this author

Jae Young Jho,

Jae Young Jho

Hyperstructured Organic Materials Research Center and School of Chemical Engineering, Seoul National University, Seoul 151-744, Korea

Search for more papers by this author

Jongok Won,

Jongok Won

Department of Applied Chemistry, Sejong University, Seoul 143-747, Korea

Search for more papers by this author

First published: 15 October 2002

https://doi.org/10.1002/pola.10516

Citations: 127

^†

NRCC No. 44387

^‡

Exclusive worldwide publication rights in the article have been transferred to Wiley Periodicals, Inc.

Share a link

Email
Wechat
Bluesky

Abstract

The commercial polyimide Matrimid was modified by bromination for the purpose of improving its membrane-transport properties as a gas-separation material and providing functional group reactivity for further modifications. The unmodified and brominated polymers were characterized by elemental analysis and one-dimensional and two-dimensional NMR, which revealed that one bromine atom per repeat unit was incorporated regioselectively onto the indane aromatic ring. The thermal and physical properties of the polymers before and after bromination were also investigated. The gas-transport properties of the unmodified and brominated polymers were compared. © 2002 Government of Canada. Exclusive worldwide publication rights in the article have been transferred to Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4193–4204, 2002

REFERENCES AND NOTES

1 Ciba Specialty Chemicals Corporation, Performance Polymers, Matrimid 5218 Resins Polyimide Factsheet, Ciba-Geigy Corporation, Brewster, NY, 1996.
Google Scholar
2 Cassidy, P. E. Thermally Stable Polymers; Marcel Dekker: New York, 1980.
Google Scholar
3 Clausi, D. T.; Koros, W. J. J Membr Sci 2000, 167, 79–89.
10.1016/S0376-7388(99)00276-8
CAS Web of Science® Google Scholar
4 Jones, C. W.; Koros, W. J. Carbon 1994, 32, 1419–1425.
10.1016/0008-6223(94)90135-X
CAS Web of Science® Google Scholar
5 Fuertes, A. B.; Nevskaia, D. M.; Centeno, T. A. Microporous Mesoporous Mater 1999, 33, 115–125.
10.1016/S1387-1811(99)00129-8
CAS Web of Science® Google Scholar
6 Bos, A.; Punt, I. G. M.; Wessling, M.; Strathmann, H. J Polym Sci Part B: Polym Phys 1998, 36, 1547–1556.
10.1002/(SICI)1099-0488(19980715)36:9<1547::AID-POLB12>3.0.CO;2-5
CAS Web of Science® Google Scholar
7 Bos, A.; Punt, I. G. M.; Wessling, M.; Strathmann, H. Sep Purif Technol 1998, 14, 27–39.
10.1016/S1383-5866(98)00057-4
CAS Web of Science® Google Scholar
8 Ekiner, O. M.; Hayes, R. A.; Va, W. U.S. Patent 5,015,270, 1991.
Google Scholar
9 Wang, I.-F.; Minhas, B. S. U.S. Patent 5,067,970, 1991.
Google Scholar
10 Simmons, J. W.; Ekiner, O. M. U.S. Patent 5,232,472, 1993.
Google Scholar
11 Macheras, J. R.; Bickson, B.; Nelson, J. D. U.S. Patent 5,443,728, 1995.
Google Scholar
12 Liou, G.-S.; Wang, J.-S. B.; Tseng, S.-T.; Tsiang, R. C.-C. J Polym Sci Part A: Polym Chem 1999, 37, 1673–1680.
10.1002/(SICI)1099-0518(19990601)37:11<1673::AID-POLA13>3.0.CO;2-5
CAS Web of Science® Google Scholar
13 Okamoto, K.-I.; Ijyuin, T.; Fujiwara, S.; Wang, H. Polym J 1998, 30, 492–498.
10.1295/polymj.30.492
CAS Web of Science® Google Scholar
14 Belfield, K. D.; Najjar, O.; Sriram, S. R. Polymer 2000, 41, 5011–5020.
10.1016/S0032-3861(99)00563-7
CAS Web of Science® Google Scholar
15 Yoshinaga, T.; Hoshino, H.; Asanuma, S.; Hirayama, S. Japanese Patent JP 6254367, 1994.
Google Scholar
16 Hayes, R. A. U.S. Patent 4,838,900, 1989.
Google Scholar
17 Okamoto, K.-I.; Tajika, M.; Matsumoto, H.; Hatano, S.; Ando, Y. Japanese Patent JP 9173801, 1997.
Google Scholar
18 Takatake, M.; Suganuma, T.; Anazawa, T. Japanese Patent JP 7236822, 1995.
Google Scholar
19 Park, J. Y.; Paul, D. R. J Membr Sci 1997, 125, 23–39.
10.1016/S0376-7388(96)00061-0
CAS Web of Science® Google Scholar
20 van Krevelen, D. W. Properties of Polymers: Their Correlation with Chemical Structure, Their Numerical Estimation and Prediction from Additive Group Contributions, 3rd ed.; Elsevier: New York, 1990.
Google Scholar
21 Grobelny, J.; Rice, D. M.; Karasz, F. E.; MacKnight, W. J. Polym Commun 1990, 31, 86–89.
CAS Web of Science® Google Scholar
22 Robeson, L. M. J Membr Sci 1991, 62, 165–185.
10.1016/0376-7388(91)80060-J
CAS Web of Science® Google Scholar
23 Koros, W. J.; Fleming, G. K.; Jordan, S. M.; Kim, T. H.; Hoehn, H. H. Prog Polym Sci 1988, 13, 339–401.
10.1016/0079-6700(88)90002-0
CAS Web of Science® Google Scholar

Citing Literature

Volume40, Issue23

1 December 2002

Pages 4193-4204

Structural characterization and gas-transport properties of brominated matrimid polyimide^† ^‡

Abstract

REFERENCES AND NOTES

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Structural characterization and gas-transport properties of brominated matrimid polyimide† ‡

Abstract

REFERENCES AND NOTES

Citing Literature

References

Related

Information

Structural characterization and gas-transport properties of brominated matrimid polyimide^† ^‡