Impact of bilayer structures on the surface passivation quality of high-rate-sputtered hydrogenated amorphous silicon for silicon heterojunction solar cells
Faris Akira Bin Mohd Zulkifly
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Search for more papers by this authorYuta Shiratori
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Search for more papers by this authorKazuyoshi Nakada
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Search for more papers by this authorCorresponding Author
Shinsuke Miyajima
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Correspondence
Shinsuke Miyajima, Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8550, Japan.
Email: [email protected]
Search for more papers by this authorFaris Akira Bin Mohd Zulkifly
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Search for more papers by this authorYuta Shiratori
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Search for more papers by this authorKazuyoshi Nakada
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Search for more papers by this authorCorresponding Author
Shinsuke Miyajima
Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8550 Japan
Correspondence
Shinsuke Miyajima, Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8550, Japan.
Email: [email protected]
Search for more papers by this authorFaris Akira Bin Mohd Zulkifly and Yuta Shiratori contributed equally to this work.
Abstract
Crystalline silicon surface passivation effect of intrinsic hydrogenated amorphous silicon (i-a-Si:H) films deposited by radio-frequency facing target sputtering (RF-FTS) using a two-step deposition technique was investigated. In the two-step deposition technique, an i-a-Si:H layer was deposited at a high sputtering power condition after the deposition of i-a-Si:H at a low sputtering power condition. The two-step deposition technique drastically improved the passivation quality of i-a-Si:H compared with a conventional single-step deposition technique. Only 0.5-nm-thick i-a-Si:H deposited at a low sputtering power suppresses the initial sputtering damage to the crystalline silicon surface. A high average deposition rate of 14.1 nm/min was also achieved. A non-textured silicon heterojunction solar cell using an i-a-Si:H passivation layer deposited by the two-step method shows a conversion efficiency of 17.4% (Voc = 0.679 V, Jsc = 35.0 mA/cm2, FF = 0.732).
REFERENCES
- 1Blakers AW, Wang A, Milne AM, Zhao J, Green MA. 22.8% efficient silicon solar cell. Appl. Phys. Lett. 1989; 55: 1363-1365. https://doi.org/10.1063/1.101596
- 2Schmidt J, Merkle A, Brendel R, Hoex B, de Sanden MV, Kessels WM. Surface passivation of high-efficiency silicon solar cells by atomic-layer-deposited Al2O3. Prog Photovoltaics Res Appl. 2008; 16(6): 461-466. https://doi.org/10.1002/pip.823
- 3Min B, Müller M, Wagner H, et al. A roadmap toward 24% efficient PERC solar cells in industrial mass production. IEEE J Photovoltaics. 2017; 7(6): 1541-1550. https://doi.org/10.1109/JPHOTOV.2017.2749007
- 4Masuko K, Shigematsu M, Hashiguchi T, et al. Achievement of more than 25% conversion efficiency with crystalline silicon heterojunction solar cell. IEEE J. Photovoltaics. 2014; 4(6): 1433-1435.
- 5Adachi D, Hernández JL, Yamamoto K. Impact of carrier recombination on fill factor for large area heterojunction crystalline silicon solar cell with 25.1% efficiency. Appl. Phys. Lett. 2015; 107: 22-25. https://doi.org/10.1063/1.4937224
- 6Yoshikawa K, Kawasaki H, Yoshida W, et al. Silicon heterojunction solar cell with interdigitated back contacts for a photoconversion efficiency over 26%. Nature Energy. 2017; 2(5):17032. https://doi.org/10.1038/nenergy.2017.32
- 7De Wolf S, Descoeudres A, Holman ZC, Ballif C. High-efficiency silicon heterojunction solar cells: a review. Green. 2012; 2(0): 7-24. https://doi.org/10.1515/green-2011-0039
- 8Liu W, Zhang L, Chen R, at al. Underdense a-Si:H film capped by a dense film as the passivation layer of a silicon heterojunction solar cell. J Appl Phys. 2016; 120(17):175301. https://doi.org/10.1063/1.4966941
- 9Sai H, Chen P, Hsu H, Matsui T, Nunomura S, Matsubara K. Impact of intrinsic amorphous silicon bilayers in silicon heterojunction solar cells. J Appl Phys. 2018; 124(10):103102. https://doi.org/10.1063/1.5045155
- 10Louwen A, van Sark WG, Schropp RE, Turkenburg WC, Faaij AP, Cost analysis of two silicon heterojunction solar cell designs, 2013 IEEE 39th Photovolt. Spec. Conf. (2013) 3357–3361. https://doi.org/10.1109/PVSC.2013.6745170
- 11Naoe M, Yamanaka S, Hoshi Y. Facing targets type of sputtering method for deposition of magnetic metal films at low temperature and high rate. IEEE Trans Magn. 1980; MAG-16: 646–648. https://doi.org/10.1109/TMAG.1980.1060683
- 12Hoshi Y, Kato HO, Funatsu K. Structure and electrical properties of ITO thin films deposited at high rate by facing target sputtering. Thin Solid Films. 2003; 445(2): 245-250. https://doi.org/10.1016/S0040-6090(03)01182-9
- 13Hoshi Y, Kobayashi SI, Uchida T, Sawada Y, Lei H. Development of low damage sputter-deposition method for the preparation of organic light emitting diode. J Vac Soc Japan (in Japanese). 2016; 59: 59-64.
- 14Yu W, Meng LH, Yuan J, Lu HJ, Wu SJ, Fu GS. Influence of substrate temperature on growth of a-Si:H films by reactive facing target sputtering deposition. Science China Physics, Mechanics and Astronomy. 2010; 53(5): 807–811. https://doi.org/10.1007/s11433-010-0193-z
- 15Descoeudres A, Barraud L, De Wolf Stefaan SB, at al. Improved amorphous/crystalline silicon interface passivation by hydrogen plasma treatment. Appl Phys Lett. 2011; 99(12):123506. https://doi.org/10.1063/1.3641899
- 16Koyama K, Ohdaira K, Matsumura H. Extremely low surface recombination velocities on crystalline silicon wafers realized by catalytic chemical vapor deposited SiNx/a-Si stacked passivation layers. Appl. Phys. Lett. 2010; 97:82108. https://doi.org/10.1063/1.3483853
- 17Nakada K, Miyajima S, Konagai M, Amorphous silicon oxide passivation films for silicon heterojunction solar cells studied by hydrogen evolution, Jpn. J. Appl. Phys. 2014; 53:04ER13. doi:https://doi.org/10.7567/JJAP.53.04ER13
- 18Zhang H, Nakada K, Miyajima S, Konagai M. High-performance a-Si1-xOx:H/c-Si heterojunction solar cells realized by the a-Si:H/a-Si1-xOx:H stack buffer layer. Phys Status Solidi RRL. 2015; 9(4): 225-229. https://doi.org/10.1002/pssr.201409546
- 19Tsuzaki S, Ohdaira K, Oikawa T, Koyama K, Matsumura H. Improvement in passivation quality and open-circuit voltage in silicon heterojunction solar cells by the catalytic doping of phosphorus atoms. Jpn. J. Appl. Phys. 2015; 54:072301. https://doi.org/10.7567/JJAP.54.072301
- 20Zhang X, Hargreaves S, Wan Y, Cuevas A. Surface passivation of crystalline silicon by sputter deposited hydrogenated amorphous silicon. Phys Status Solidi – Rapid Res Lett. 2014; 8(3): 231-234. https://doi.org/10.1002/pssr.201308253
- 21Zhang X, Cuevas A, Demaurex B, De Wolf S. Sputtered hydrogenated amorphous silicon for silicon heterojunction solar cell fabrication. Energy Procedia. 2014; 55: 865-872. https://doi.org/10.1016/j.egypro.2014.08.070
- 22Shiratori Y, Zulkifly FA, Nakada K, Miyajima S. Effect of RF power on the properties of intrinsic hydrogenated amorphous silicon passivation layer deposited by facing target sputtering. Appl Phys Express. 2018; 11(3):31301. https://doi.org/10.7567/APEX.11.031301
- 23Shiratori, Y., Kim, J., Nakada, K. and Miyajima, S., Silicon heterojunction solar cell with intrinsic hydrogenated amorphous silicon layer deposited by facing target sputtering, 2018 IEEE 7th World Conf. Photovolt. Energy Conversion, WCPEC 2018 - A Jt. Conf. 45th IEEE PVSC, 28th PVSEC 34th EU PVSEC. (2018) 3142–3147. doi:https://doi.org/10.1109/PVSC.2018.8547972
- 24Jellison GE Jr, Modine FA. Parameterization of the optical functions of amorphous materials in the interband region. Appl Phys Lett. 1996; 69(3): 371-373. http://link.aip.org/link/?APL/69/371/1
- 25Shiratori Y, Nakada K, Miyajima S. Effect of superimposed DC power on the properties of intrinsic hydrogenated amorphous silicon passivation layer deposited by RF facing target sputtering. IEEE J. Photovoltaics. 2020. https://doi.org/10.1109/jphotov.2020.2989174
- 26Kim J, Takiguchi Y, Nakada K, Miyajima S, Silicon heterojunction solar cells with Cu2O:N as p-type layer, 2018 IEEE 7th World Conf. Photovolt. Energy Convers. (A Jt. Conf. 45th IEEE PVSC, 28th PVSEC 34th EU PVSEC). (2018) 2145–2150.
- 27Ateto EO, Konagai M, Miyajima S. Triple layer antireflection design concept for the front side of c-Si heterojunction solar cell based on the antireflective effect of nc-3C-SiC:H emitter layer. Int J Photoenergy. 2016; 2016:5282851hyphen;5282859. https://doi.org/10.1155/2016/5282851