Volume 71, Issue 12 pp. 2011-2020
ARTICLE

One-pot fluorine-free superhydrophobic surface towards corrosion resistance and water droplet bouncing

Binbin Zhang

Corresponding Author

Binbin Zhang

CAS Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, China

Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao, China

Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao, China

Correspondence Binbin Zhang and Jie Zhang, CAS Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, No. 7 Nanhai Road, 266071 Qingdao, China.

Email: [email protected] (B. Z.) and [email protected] (J. Z.)

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Jia Wang

Jia Wang

CAS Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, China

University of Chinese Academy of Sciences, Beijing, China

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Jie Zhang

Corresponding Author

Jie Zhang

CAS Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, China

Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao, China

Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao, China

Correspondence Binbin Zhang and Jie Zhang, CAS Key Laboratory of Marine Environmental Corrosion and Bio-Fouling, Institute of Oceanology, Chinese Academy of Sciences, No. 7 Nanhai Road, 266071 Qingdao, China.

Email: [email protected] (B. Z.) and [email protected] (J. Z.)

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First published: 25 June 2020
Citations: 6

Abstract

The drawbacks of artificial fabrication methods of superhydrophobic surface including multistep operations, time-consuming and fluorine-containing chemicals employment lead to inefficient preparation, severe environmental pollution, and safety concerns, restricting the large-scale manufacturing and promising applications. Herein, a fluorine-free stearic acid-based one-pot hydrothermal strategy was employed to simultaneously achieve surface roughness and low surface energy, transforming the surface wettability from hydrophilicity to superhydrophobicity. The as-fabricated superhydrophobic 5083 Al alloy surface exhibits excellent water-droplet bouncing, ultralow surface adhesion force, and repeatable self-cleaning ability. The electrochemical impedance spectroscopy results reveal that the impedance modulus value |Z|0.01 Hz was remarkably improved, demonstrating a high-efficiency corrosion resistance. We believe that the one-pot fluorine-free hydrothermal-fabricated superhydrophobic surface can be considered as an efficient barrier against corrosive environments, and being beneficial for the functional applications of metallic materials.

CONFLICT OF INTERESTS

The authors declare that there are no conflict of interests.

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