From 1D to 3D: Fabrication of CH3NH3PbI3 Perovskite Solar Cell Thin Films from (Pyrrolidinium)PbI3 via Organic Cation Exchange Approach
Yu Miao
School of Science, Beijing Jiaotong University, Beijing, 100044 P. R. China
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorHaochen Fan
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorPengcheng Wang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorYue Zhang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCaiyan Gao
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorLian-Ming Yang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorYanLin Song
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Chunhe Yang
School of Science, Beijing Jiaotong University, Beijing, 100044 P. R. China
Search for more papers by this authorCorresponding Author
Cai-Ming Liu
Organic Solids Laboratory, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Ke-jian Jiang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorYu Miao
School of Science, Beijing Jiaotong University, Beijing, 100044 P. R. China
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorHaochen Fan
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorPengcheng Wang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorYue Zhang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCaiyan Gao
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorLian-Ming Yang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorYanLin Song
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Chunhe Yang
School of Science, Beijing Jiaotong University, Beijing, 100044 P. R. China
Search for more papers by this authorCorresponding Author
Cai-Ming Liu
Organic Solids Laboratory, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Ke-jian Jiang
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorAbstract
A new crystal form of 1D perovskite (pyrrolidinium)PbI3 (orthorhombic phase) is synthesized and characterized. The 1D perovskite has a good film formability by solution spin coating and is in situ transformed to 3D CH3NH3PbI3 via the organic cation exchange approach in CH3NH2 atmosphere, which is dense and uniform. The converted 3D perovskite film is used as a light absorber, and the corresponding perovskite solar cell shows a power conversion efficiency of up to 19.2% under simulated 1 sun AM1.5G illumination (100 mW cm−2).
Conflict of Interest
The authors declare no conflict of interest.
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