Heterogeneous Organic Polymers Embedded with Chiral Bisoxazoline Ligands for Photoinduced Cu-Catalyzed Asymmetric Cyanation
Ren-Jie Yu
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
‡ These authors contributed equally to this work.
Search for more papers by this authorRui-Rui Zhao
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
‡ These authors contributed equally to this work.
Search for more papers by this authorFang Hu
State Key Laboratory of Chemical Oncogenomics, Key Laboratory of Chemical Biology, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, Guangdong, 518055 China
Search for more papers by this authorCorresponding Author
Zhen Su
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
E-mail [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Ke Gao
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
E-mail [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Liang-Qiu Lu
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, Gansu, 730000 China
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, 453007 China
E-mail [email protected]; [email protected]; [email protected]Search for more papers by this authorWen-Jing Xiao
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
Search for more papers by this authorRen-Jie Yu
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
‡ These authors contributed equally to this work.
Search for more papers by this authorRui-Rui Zhao
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
‡ These authors contributed equally to this work.
Search for more papers by this authorFang Hu
State Key Laboratory of Chemical Oncogenomics, Key Laboratory of Chemical Biology, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, Guangdong, 518055 China
Search for more papers by this authorCorresponding Author
Zhen Su
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
E-mail [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Ke Gao
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
E-mail [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Liang-Qiu Lu
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, Gansu, 730000 China
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, 453007 China
E-mail [email protected]; [email protected]; [email protected]Search for more papers by this authorWen-Jing Xiao
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei, 430079 China
Wuhan Institute of Photochemistry and Technology, Wuhan, Hubei, 430082 China
Search for more papers by this authorComprehensive Summary
Chiral bisoxazoline (box) ligands with indene groups at C4 and C5 are highly potent in asymmetric catalysis, but face challenges in terms of cost and recyclability. To address this, we have designed polystyrene-supported box ligands by modifying the indene moiety instead of the traditional methylene bridge. This design preserves the necessary steric environment for copper coordination, enabling high efficiency and excellent enantioselectivity as examined in photoinduced asymmetric cyanation reactions. The resulting copper complexes are robust and recyclable, maintaining performance over five cycles. This approach provides a sustainable and practical solution for asymmetric catalysis with chiral box ligands.
Supporting Information
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Appendix S1: Supporting Information |
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