Iron(III) Chloride Catalyzed Oxidative Coupling Reaction of 1,2-Diarylethylene Derivatives
Derong Ji
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorLidan Su
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorKeqing Zhao
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorBiqin Wang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorPing Hu
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorChun Feng
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorShikai Xiang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorCorresponding Author
Hua Yang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China, Tel.: 0086-028-84760802Search for more papers by this authorCorresponding Author
Chenggang Zhang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China, Tel.: 0086-028-84760802Search for more papers by this authorDerong Ji
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorLidan Su
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorKeqing Zhao
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorBiqin Wang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorPing Hu
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorChun Feng
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorShikai Xiang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
Search for more papers by this authorCorresponding Author
Hua Yang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China, Tel.: 0086-028-84760802Search for more papers by this authorCorresponding Author
Chenggang Zhang
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China
College of Chemistry and Materials, Sichuan Normal University, Chengdu, Sichuan 610066, China, Tel.: 0086-028-84760802Search for more papers by this authorAbstract
A nontoxic FeCl3 catalyzed intramolecular oxidative coupling reaction was developed for mild synthesis of a series of phenanthrenes with different substituents. The method involves cross dehydrogenative coupling of a variety of 1,2-diarylethylene derivatives with di-tert-butylperoxide (DTBP) as a sole oxidant at room temperature in CH2Cl2/TFA (9:1 V/V) to yield phenanthrenes in good to excellent yields.
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