Syntheses, Structures and Properties of Four New Transitional Metal Complexes Based on Benzotriazole-5-carboxylic Acid
Yang Li
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorCorresponding Author
Changyan Sun
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China, Tel.: 0086-010-62333871; Fax: 0086-010-62332126Search for more papers by this authorWenjun Li
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorHualei Zhou
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorBin Dong
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorYang Li
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorCorresponding Author
Changyan Sun
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China, Tel.: 0086-010-62333871; Fax: 0086-010-62332126Search for more papers by this authorWenjun Li
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorHualei Zhou
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorBin Dong
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Search for more papers by this authorAbstract
Four new complexes, [Zn(btca)(2,2′-bpy)] (1), [Mn(btca)(2,2′-bpy)] (2), [Co(btca)(phen)] (3), and [Cu(btca)(phen)] (4), (H2btca=benzotriazole-5-carboxylic acid, 2,2′-bpy=2,2′-bipyridine, phen=1,10-phenanthroline), were successfully synthesized and characterized by elemental analysis, single crystal X-ray diffraction, and IR spectroscopy. Complexes 1–4 crystallize in the orthorhombic system with space group of Pbca and show similar 2D layers, which are interlinked to supramolecular networks by π-π stacking interactions. Furthermore, TGA curves show that complexes 1–4 have good thermal stability. Solid-state fluorescent property of complex 1 was also investigated at room temperature.
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