Analysis of Membrane Reactors for Integrated Coupling of Oxidative and Thermal Dehydrogenation of Propane
Corresponding Author
Andreas Brune
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany
Correspondence: Andreas Brune ([email protected]), Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany.Search for more papers by this authorTanya Wolff
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorAndreas Seidel-Morgenstern
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorChristof Hamel
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany
Search for more papers by this authorCorresponding Author
Andreas Brune
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany
Correspondence: Andreas Brune ([email protected]), Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany.Search for more papers by this authorTanya Wolff
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorAndreas Seidel-Morgenstern
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstraße 1, 39106 Magdeburg, Germany
Search for more papers by this authorChristof Hamel
Otto von Guericke University Magdeburg, Institute of Process Engineering, Universitätsplatz 2, 39106 Magdeburg, Germany
Anhalt University of Applied Sciences, Process Engineering, Bernburger Straße 55, 06354 Köthen, Germany
Search for more papers by this authorAbstract
This study presents strategies capable to intensify the thermal dehydrogenation of propane (TDH) using integrated reactor concepts. An inert packed bed membrane reactor for distributed dosing of oxygen to realize the oxidative dehydrogenation (ODH) was studied and compared to a reactor with catalytically active membrane. The latter concept allows to combine TDH and ODH in one apparatus to overcome the chemical equilibrium by in situ conversion of the by-product H2 using O2 or in a reverse water-gas shift reaction by CO2. If CO2 is used as active sweep gas the reactor offered better performance regarding yield and selectivity. Strategies for further thermal integration are discussed.
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