Selective Liquid Phase Adsorption of Biogenic HMF on Hydrophobic Spherical Activated Carbons
Kai Schute
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
Search for more papers by this authorYannik Louven
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
Search for more papers by this authorChaline Detoni
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
Federal University of Rio de Janeiro, Chemistry School, University City, Technology Center, Block E, Rio de Janeiro, RJ 21945-970, Brazil.
Search for more papers by this authorCorresponding Author
Marcus Rose
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorKai Schute
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
Search for more papers by this authorYannik Louven
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
Search for more papers by this authorChaline Detoni
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
Federal University of Rio de Janeiro, Chemistry School, University City, Technology Center, Block E, Rio de Janeiro, RJ 21945-970, Brazil.
Search for more papers by this authorCorresponding Author
Marcus Rose
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, Germany
RWTH Aachen University, Institut für Technische und Makromolekulare Chemie, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorAbstract
The adsorption of biogenic hydroxymethylfurfural and fructose from aqueous phase reaction mixtures on polymer-based spherical activated carbons was studied. The adsorbents show a high capacity in combination with an outstanding selectivity due to their hydrophobic surface. Equilibrium isotherms and breakthrough curves of single and multicomponent solutions as well as the desorption behavior were measured and modelled accordingly. Overall, the results obtained enable further process development for adsorptive liquid phase separation in future biorefinery processes.
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