Übersichtsbeitrag
Characterization of the Oxidation States of Supported Gold Species by IR Spectroscopy of Adsorbed CO
M. Mihaylov Dr.,
H. Knözinger Prof. Dr.,
K. Hadjiivanov Prof. Dr.,
B. C. Gates Prof. Dr.,
M. Mihaylov Dr.
Department Chemie und Biochemie, Physikalische Chemie, LMU München, Butenandtstrasse 5-13 (Haus E), D-81377 München, Germany
Search for more papers by this authorH. Knözinger Prof. Dr.
Department Chemie und Biochemie, Physikalische Chemie, LMU München, Butenandtstrasse 5-13 (Haus E), D-81377 München, Germany
Search for more papers by this authorK. Hadjiivanov Prof. Dr.
Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia 1113, Bulgaria
Search for more papers by this authorB. C. Gates Prof. Dr.
Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 USA
Search for more papers by this authorM. Mihaylov Dr.,
H. Knözinger Prof. Dr.,
K. Hadjiivanov Prof. Dr.,
B. C. Gates Prof. Dr.,
M. Mihaylov Dr.
Department Chemie und Biochemie, Physikalische Chemie, LMU München, Butenandtstrasse 5-13 (Haus E), D-81377 München, Germany
Search for more papers by this authorH. Knözinger Prof. Dr.
Department Chemie und Biochemie, Physikalische Chemie, LMU München, Butenandtstrasse 5-13 (Haus E), D-81377 München, Germany
Search for more papers by this authorK. Hadjiivanov Prof. Dr.
Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia 1113, Bulgaria
Search for more papers by this authorB. C. Gates Prof. Dr.
Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 USA
Search for more papers by this authorAbstract
The use of IR spectroscopy of adsorbed CO for determination of gold speciation on supported gold catalysts is reviewed. Different ionic and metallic sites (Au3+, Au+, Au0, and Au–) can be differentiated on the basis of the frequency and stability of their surface carbonyl species formed after CO adsorption. In addition, the study of CO adsorption and reaction with other gases can provide unique information on the mechanisms of catalytic reactions with participation of CO. Finally, results from complementary techniques such as X-ray absorption spectroscopy, also useful for determination of gold oxidation state, are briefly considered.
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