Separation of Trimethyl Borate from a Liquid Mixture by Pervaporation
Jana Gaálová
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorLukáš Vojtek
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorSara Lasnier
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorToma Tadic
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorJan Sýkora
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorCorresponding Author
Pavel Izák
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Correspondence: Pavel Izák ([email protected]), Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic.Search for more papers by this authorJana Gaálová
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorLukáš Vojtek
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorSara Lasnier
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorToma Tadic
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorJan Sýkora
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Search for more papers by this authorCorresponding Author
Pavel Izák
Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic
Correspondence: Pavel Izák ([email protected]), Institute of Chemical Process Fundamentals of the ASCR, v.v.i., Rozvojova 135, 165 00 Prague, Czech Republic.Search for more papers by this authorAbstract
Four commercial polyvinyl alcohol (PVA) and polydimethylsiloxane (PDMS) membranes were applied to the pervaporation of an azeotropic mixture containing trimethyl borate, a precursor to boronic acids used in Suzuki couplings and a gaseous anti-oxidant in solder flux or brazing. The degree of cross-linking of the chains in the active layer played a crucial role in the membrane process using the membranes PERVAP 4155-80, PERVAP 4155-40 and PERVAP 4155-30. PERVAP 4155-30 reached the best results from all tested membranes; an impressive selectivity with fast permeation was also achieved with the PERVAP 4060 membrane. Methanol preferentially passed through PERVAP 4155-30, but trimethyl borate was favorably pervaporated from the mixture by PERVAP 6040, due to the diverse affinities of the membranes.
References
- 1 P. Shao, R. Y. M. Huang, J. Membr. Sci. 2007, 287 (2), 162–179. DOI: https://doi.org/10.1016/j.memsci.2006.10.043
- 2 P. Izák, M. Köckerling, U. Kragl, Desalination 2006, 199 (1), 96–98. DOI: https://doi.org/10.1016/j.desal.2006.03.151
- 3 S.-L. Wee, C.-T. Tye, S. Bhatia, Sep. Purif. Technol. 2008, 63 (3), 500–516. DOI: https://doi.org/10.1016/j.seppur.2008.07.010
- 4 Y. K. Ong, G. M. Shi, N. L. Le, Y. P. Tang, J. Zuo, S. P. Nunes, T.-S. Chung, Progr. Polym. Sci. 2016, 57, 1–31. DOI: https://doi.org/10.1016/j.progpolymsci.2016.02.003
- 5
S. Curcio, G. De Luca, K. Saha, S. Chakraborty, in Membrane Technologies for Biorefining (Eds: A. Figoli, A. Cassano, A. Basile), Woodhead Publishing, Sawston
2016, 3–28.
10.1016/B978-0-08-100451-7.00001-3 Google Scholar
- 6 E. Haaz, A. J. Toth, Sep. Purif. Technol. 2018, 205, 121–129. DOI: https://doi.org/10.1016/j.seppur.2018.04.088
- 7 R. Meyer, D. A. Figueroa Paredes, M. Fuentes, A. Amelio, B. Morero, P. Luis, B. Van der Bruggen, J. Espinosa, Sep. Purif. Technol. 2016, 158, 238–249. DOI: https://doi.org/10.1016/j.seppur.2015.12.024
- 8 B. Smith, D. Suhanya, S. Sridhar, M. Ramakrishna, J. Membr. Sci. 2004, 241 (1), 1–21. DOI: https://doi.org/10.1016/j.memsci.2004.03.042
- 9 H.-M. Jung, J. Y. Lee, J.-H. Lee, M.-K. Oh, Bioresour. Technol. 2018, 259, 373–380. DOI: https://doi.org/10.1016/j.biortech.2018.03.081
- 10
N. G. Kanse, S. D. Dawande, P. B. Dhanke, Mater. Today Proc.
2018, 5 (2, Part 1), 3541–3550. DOI: https://doi.org/10.1016/j.matpr.2017.11.602
10.1016/j.matpr.2017.11.602 Google Scholar
- 11
N. G. Kanse, S. D. Dawande, Mater. Today Proc.
2017, 4 (9), 10520–10523. DOI: https://doi.org/10.1016/j.matpr.2017.06.412
10.1016/j.matpr.2017.06.412 Google Scholar
- 12 M. E. Dmitrenko, A. V. Penkova, A. I. Kuzminova, M. Morshed, M. I. Larionov, H. Alem, A. A. Zolotarev, S. S. Ermakov, D. Roizard, Appl. Surf. Sci. 2018, 450, 527–537. DOI: https://doi.org/10.1016/j.apsusc.2018.04.169
- 13 W. Kaminski, J. Marszalek, E. Tomczak, Desalination 2018, 433, 89–93. DOI: https://doi.org/10.1016/j.desal.2018.01.014
- 14 Y. Wang, X. Mei, T. Ma, C. Xue, M. Wu, M. Ji, Y. Li, J. Cleaner Prod. 2018, 197, 742–749. DOI: https://doi.org/10.1016/j.jclepro.2018.06.239
- 15 A. Figoli, A. Cassano, A. Basile, Membrane Technologies for Biorefining, Woodhead Publishing, Sawston 2016, 301–320.
- 16 S. Lux, T. Winkler, M. Körbler, M. Siebenhofer, Chem. Eng. Sci. 2017, 158, 500–508. DOI: https://doi.org/10.1016/j.ces.2016.10.034
- 17 Pervaporation Membrane Separation Processes (Ed: R. Y. M. Huang), Elsevier, Amsterdam 1991, pp. 322–323.
- 18 X. He, T. Wang, Y. Li, J. Chen, J. Li, J. Membr. Sci. 2018, 563, 447–459. DOI: https://doi.org/10.1016/j.memsci.2018.06.015
- 19 M. Žák, M. Klepic, L. Č. Štastná, Z. Sedláková, H. Vychodilová, Š. Hovorka, K. Friess, A. Randová, L. Brožová, J. C. Jansen, M. R. Khdhayyer, P. M. Budd, P. Izák, Sep. Purif. Technol. 2015, 151, 108–114. DOI: https://doi.org/10.1016/j.seppur.2015.07.041
- 20 Y. Zhang, S. Chen, R. Shi, P. Du, X. Qiu, X. Gu, Sep. Purif. Technol. 2018, 204, 234–242. DOI: https://doi.org/10.1016/j.seppur.2018.04.066
- 21 N. Moriyama, H. Nagasawa, M. Kanezashi, T. Tsuru, Sep. Purif. Technol. 2018, 207, 108–115. DOI: https://doi.org/10.1016/j.seppur.2018.06.021
- 22 S. Sorribas, A. Kudasheva, E. Almendro, B. Zornoza, Ó. de la Iglesia, C. Téllez, J. Coronas, Chem. Eng. Sci. 2015, 124, 37–44. DOI: https://doi.org/10.1016/j.ces.2014.07.046
- 23 H.-A. Tsai, C.-Y. Hsu, S.-H. Huang, K.-R. Lee, W.-S. Hung, C.-C. Hu, J.-Y. Lai, J. Taiwan Inst. Chem. Eng. 2018, 91, 623–633. DOI: https://doi.org/10.1016/j.jtice.2018.06.023
- 24www.ilo.org/dyn/icsc/showcard.display?p_version=2&p_card_id=0593 (Accessed on May 16, 2019)
