Improving the migration resistance against phthalate plasticizer in polyvinyl chloride/graphene oxide composites
XingBao Chen
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Data curation (supporting), Formal analysis (equal), Investigation (equal), Writing - original draft (supporting)
Search for more papers by this authorXudong Wu
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Investigation (equal)
Search for more papers by this authorShiwei Zhao
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Conceptualization (equal)
Search for more papers by this authorYuan Lei
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Investigation (equal)
Search for more papers by this authorShiyi Zhou
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, China
Contribution: Software (supporting)
Search for more papers by this authorCorresponding Author
Jingxin Lei
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Correspondence
Jingxin Lei and Liang Jiang, State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
Email: [email protected] and [email protected]
Contribution: Funding acquisition (lead), Methodology (equal)
Search for more papers by this authorCorresponding Author
Liang Jiang
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Correspondence
Jingxin Lei and Liang Jiang, State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
Email: [email protected] and [email protected]
Contribution: Data curation (lead), Formal analysis (equal), Funding acquisition (lead), Methodology (lead)
Search for more papers by this authorXingBao Chen
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Data curation (supporting), Formal analysis (equal), Investigation (equal), Writing - original draft (supporting)
Search for more papers by this authorXudong Wu
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Investigation (equal)
Search for more papers by this authorShiwei Zhao
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Conceptualization (equal)
Search for more papers by this authorYuan Lei
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Contribution: Investigation (equal)
Search for more papers by this authorShiyi Zhou
College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, China
Contribution: Software (supporting)
Search for more papers by this authorCorresponding Author
Jingxin Lei
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Correspondence
Jingxin Lei and Liang Jiang, State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
Email: [email protected] and [email protected]
Contribution: Funding acquisition (lead), Methodology (equal)
Search for more papers by this authorCorresponding Author
Liang Jiang
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, China
Correspondence
Jingxin Lei and Liang Jiang, State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
Email: [email protected] and [email protected]
Contribution: Data curation (lead), Formal analysis (equal), Funding acquisition (lead), Methodology (lead)
Search for more papers by this authorAbstract
Phthalic plasticizer plays an important role in processing and manufacturing one of the universal polymer materials, poly (vinyl chloride) (PVC), which has been widely applied in every aspect of our lives. However, there still exists the intrinsic problem in migration resistance of phthalic plasticizer in long-term use. In this work, we take a facile and convenient approach by incorporating commercial graphene oxide (GO) into PVC matrix to prepare polyvinyl chloride/graphene oxide (PVC/GO) composites, forming a sheet structure for improving the migration resistance of phthalic plasticizer. The advantages of GO that has abundant oxygen-containing groups on its surface, including carboxyl groups at the sheet edges, epoxy groups, and hydroxyl groups on its basal planes. Especially, these oxygen-containing groups in GO are beneficial to blend with long molecular chain of PVC and the sheet structure of GO can prevent phthalic plasticizer migrating from interior PVC. Addition of GO not only effectively enhanced the mechanical properties of PVC/GO composites but also improve their migration resistance due to the sheet structure. This strategy provides an attractive way to solve the problem of migration of plasticizer with simple incorporation GO into the matrix of PVC, reinforcing the composite properties and broadening its applied fields.
CONFLICT OF INTEREST STATEMENT
There are no conflicts to declare.
Open Research
DATA AVAILABILITY STATEMENT
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
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| app54742-sup-0001-FiguresS1-S5.docxWord 2007 document , 1.4 MB | Figure S1 |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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