Construction of a novel double network polymer composite and evaluation of its highly efficient adsorption properties for copper ions
Xiaoqiong Wu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Investigation (equal)
Search for more papers by this authorYutong Song
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Investigation (equal)
Search for more papers by this authorCorresponding Author
Ping Yin
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Correspondence
Ping Yin, Qiang Xu, and Zhenglong Yang, School of Chemistry and Materials Science, Ludong University, Yantai 264025, People's Republic of China.
Email: [email protected]; [email protected]; [email protected]
Contribution: Project administration (lead), Writing - original draft (lead), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Qiang Xu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Correspondence
Ping Yin, Qiang Xu, and Zhenglong Yang, School of Chemistry and Materials Science, Ludong University, Yantai 264025, People's Republic of China.
Email: [email protected]; [email protected]; [email protected]
Contribution: Resources (equal)
Search for more papers by this authorCorresponding Author
Zhenglong Yang
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Correspondence
Ping Yin, Qiang Xu, and Zhenglong Yang, School of Chemistry and Materials Science, Ludong University, Yantai 264025, People's Republic of China.
Email: [email protected]; [email protected]; [email protected]
Contribution: Project administration (equal)
Search for more papers by this authorYanbin Xu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Resources (equal)
Search for more papers by this authorXiguang Liu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Writing - review & editing (equal)
Search for more papers by this authorFeng Wang
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Resources (equal)
Search for more papers by this authorYing Wang
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Writing - review & editing (supporting)
Search for more papers by this authorWenjuan Sun
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Investigation (supporting)
Search for more papers by this authorHonglan Cai
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Formal analysis (supporting), Investigation (supporting)
Search for more papers by this authorXiaoqiong Wu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Investigation (equal)
Search for more papers by this authorYutong Song
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Investigation (equal)
Search for more papers by this authorCorresponding Author
Ping Yin
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Correspondence
Ping Yin, Qiang Xu, and Zhenglong Yang, School of Chemistry and Materials Science, Ludong University, Yantai 264025, People's Republic of China.
Email: [email protected]; [email protected]; [email protected]
Contribution: Project administration (lead), Writing - original draft (lead), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Qiang Xu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Correspondence
Ping Yin, Qiang Xu, and Zhenglong Yang, School of Chemistry and Materials Science, Ludong University, Yantai 264025, People's Republic of China.
Email: [email protected]; [email protected]; [email protected]
Contribution: Resources (equal)
Search for more papers by this authorCorresponding Author
Zhenglong Yang
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Correspondence
Ping Yin, Qiang Xu, and Zhenglong Yang, School of Chemistry and Materials Science, Ludong University, Yantai 264025, People's Republic of China.
Email: [email protected]; [email protected]; [email protected]
Contribution: Project administration (equal)
Search for more papers by this authorYanbin Xu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Resources (equal)
Search for more papers by this authorXiguang Liu
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Writing - review & editing (equal)
Search for more papers by this authorFeng Wang
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Resources (equal)
Search for more papers by this authorYing Wang
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Writing - review & editing (supporting)
Search for more papers by this authorWenjuan Sun
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Investigation (supporting)
Search for more papers by this authorHonglan Cai
School of Chemistry and Materials Science, Ludong University, Yantai, People's Republic of China
Contribution: Formal analysis (supporting), Investigation (supporting)
Search for more papers by this authorFunding information: National Natural Science Foundation of China, Grant/Award Numbers: 51673090, 21806070, 51903114, 51102127; Natural Science Foundation of Shandong Province, Grant/Award Number: ZR2018PB017; Science and Technology Development Plan from Shandong Provincial Education Department, Grant/Award Number: J17KA006
Abstract
To explore more efficient heavy metal copper ions adsorbents with double network polymers, this work has presented the novel fabrication processes of the polymer composite diatomaceous earth/polydopamine-polyethyleneimine/alginate DE@PDA-PEI@SA, which was characterized by FT-IR, SEM, EDS, XPS, and was efficiently utilized for copper ions adsorption. The relevant adsorption behaviors of DE@PDA-PEI@SA for copper ions such as the effect of pH, the effect of adsorbent dosage, adsorption kinetics, adsorption isotherm etc. have been investigated. The results reveal that the adsorption kinetics of DE@PDA-PEI@SA for copper ions at different temperatures can be modeled by the pseudo second-order rate equation, the experimental data fit well with the Langmuir isotherm model, indicating a homogeneous monolayer adsorption, and the maximum adsorption capacity of DE@PDA-PEI@SA for copper ions could reach 454.55 mg/g at 35°C that is very high compared to other reported adsorbent materials. The research results indicate that DE@PDA-PEI@SA is a novel efficient adsorbent with high efficiency in wastewater treatment and water purification, which could provide a facile processing for copper adsorption.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Open Research
DATA AVAILABILITY STATEMENT
The authors confirm that the data supporting the findings of this study are available within the article.
Supporting Information
| Filename | Description |
|---|---|
| app53007-sup-0001-Figures.docxWord 2007 document , 4.1 MB | Figure S1 Influence of different DE-based fillers and PEI/SA modification methods on adsorption capacity of the polymer composite DE@PDA-PEI@SA for copper ions Figure S2 The influence of the mass ratio of DE and SA, and the molecular weight of PEI on the adsorption of the polymer composite DE@PDA-PEI@SA for copper ions Figure S3 TG curve of the polymer composite DE@PDA-PEI@SA Figure S4 Photos of dry samples of DE@PDA-PEI@SA (inset: wet samples) Figure S5 SEM of the samples after pore-forming (a), before pore-forming (b), and PEI@SA Figure S6 N2 adsorption–desorption isotherms and the corresponding pore size distribution of DE@PDA-PEI@SA Figure S7 Reusability of DE@PDA-PEI@SA for copper ions removal. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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