Polybutylene terephthalate modified with dimer acid methyl ester derived from fatty acid methyl esters and its use as a hot-melt adhesive
A Ryeon Kim
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorMin Su Park
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Search for more papers by this authorSangjun Lee
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Present address: Yoo Sung Chem. R&T Co., Ltd., 14 Sinpyeonggongdan 1-ro, Chubu-myeon, Geumsan-gun, Chungcheongnam-do, 32710, Republic of KoreaSearch for more papers by this authorMirae Ra
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Search for more papers by this authorJihoon Shin
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Search for more papers by this authorCorresponding Author
Young-Wun Kim
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Correspondence to: Y.-W. Kim (E-mail: [email protected])Search for more papers by this authorA Ryeon Kim
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Search for more papers by this authorMin Su Park
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Search for more papers by this authorSangjun Lee
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Present address: Yoo Sung Chem. R&T Co., Ltd., 14 Sinpyeonggongdan 1-ro, Chubu-myeon, Geumsan-gun, Chungcheongnam-do, 32710, Republic of KoreaSearch for more papers by this authorMirae Ra
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Search for more papers by this authorJihoon Shin
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Search for more papers by this authorCorresponding Author
Young-Wun Kim
Environment & Sustainable Resources Research Center, Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114 Republic of Korea
Department of Advanced Materials & Chemical Engineering, University of Science & Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113 Republic of Korea
Correspondence to: Y.-W. Kim (E-mail: [email protected])Search for more papers by this authorABSTRACT
A series of polyester copolymers was synthesized via melt polycondensation of dimethyl terephthalate (DMT), dimethyl isophthalate (DMI), and 1,4-butanediol (BDO) with dimer acid methyl ester (DAME) monomers, previously prepared by the Diels–Alder reaction of fatty acid methyl esters (FAMEs). We obtained copolymers with the desired composition and a high molar mass characterized by 1H NMR, FT-IR, and SEC. The relationship among the composition, thermal behavior, mechanical properties, and adhesion properties of these copolymers was examined, demonstrating that the DAME-modified copolymers could be substituted for HMA applications and are comparable to petroleum-based commercial products. As a result, these polyesters could offer improved sustainability and performance and may be good candidates for hot-melt adhesive materials. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48474.
CONFLICT OF INTEREST
The authors declare no competing financial interest.
Supporting Information
| Filename | Description |
|---|---|
| app48474-sup-0001-FigureS1.jpgJPEG image, 371.9 KB | Figure S1 FT-IR spectra of (a) DAME, (b) DMT, (c) DMI, and (d) BDO. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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