Incorporation of an Anion-Coordinated Triple Helicate into a Thin Film for Choline Recognition in an Aqueous System
Mingli Lian
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorDr. Jie Zhao
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, 710055 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorDr. Dan Zhang
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorSheng Ye
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorYidan Li
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Dong Yang
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
Search for more papers by this authorProf. Dr. Xiao-Juan Yang
Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 102488 Beijing, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Biao Wu
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 102488 Beijing, China
Search for more papers by this authorMingli Lian
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorDr. Jie Zhao
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, 710055 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorDr. Dan Zhang
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorSheng Ye
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
These authors contributed equally to this work.
Search for more papers by this authorYidan Li
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Dong Yang
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
Search for more papers by this authorProf. Dr. Xiao-Juan Yang
Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 102488 Beijing, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Biao Wu
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 102488 Beijing, China
Search for more papers by this authorGraphical Abstract
A series of ‘aniono’ helicates have been formed by the coordination of tetraphenylethene-decorated anion-binding ligand with phosphate ions. The triple helicates can be solution-processed with a polymethyl methacrylate matrix to generate functional thin films with multiple optical properties and used to recognize choline and its derivatives in water.
Abstract
Functional thin films, being fabricated by incorporating discrete supramolecular architectures, have potential applications in research areas such as sensing, energy storage, catalysis, and optoelectronics. Here, we have determined that an anion-coordinated triple helicate can be solution-processed into a functional thin film by incorporation into a polymethyl methacrylate (PMMA) matrix. The thin films fabricated by the incorporation of the anion-coordinated triple helicate show multiple optical properties, such as fluorescence, CD, and CPL. In addition, the film has the ability to recognize choline and choline derivatives in a water system. The successful recognition of Ch+ by the film represents the first example of utilizing ‘aniono’-supramolecular architectures for biomolecule detection in aqueous solution and opens up a new route for designing biocompatible functional materials.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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