Dynamically Modulating the Dissymmetry Factor of Circularly Polarized Organic Ultralong Room-Temperature Phosphorescence from Soft Helical Superstructures
Dr. Jiao Liu
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
These authors contributed equally to this work.
Contribution: Conceptualization (equal), Data curation (equal), Visualization (equal), Writing - original draft (equal)
Search for more papers by this authorJun-Jie Wu
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
These authors contributed equally to this work.
Contribution: Conceptualization (equal), Data curation (equal), Visualization (equal)
Search for more papers by this authorDr. Juan Wei
State Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
These authors contributed equally to this work.
Contribution: Conceptualization (equal), Data curation (equal), Visualization (equal)
Search for more papers by this authorZhi-Jun Huang
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Data curation (supporting), Formal analysis (supporting), Visualization (supporting)
Search for more papers by this authorXin-Yu Zhou
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Data curation (supporting), Formal analysis (supporting), Visualization (supporting)
Search for more papers by this authorDr. Jin-Ying Bao
Key Laboratory of Polymer Chemistry and Physics of, Ministry of Education Peking University, Beijing, 100871 P. R. China
Contribution: Data curation (supporting)
Search for more papers by this authorProf. Dr. Ruo-Chen Lan
Institute of Advanced Materials, Jiangxi Normal University, Nanchang, 330022 China
Contribution: Data curation (supporting), Writing - review & editing (supporting)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yun Ma
State Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Prof. Dr. Bing-Xiang Li
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Writing - review & editing (lead)
Search for more papers by this authorProf. Dr. Huai Yang
Key Laboratory of Polymer Chemistry and Physics of, Ministry of Education Peking University, Beijing, 100871 P. R. China
Contribution: Data curation (supporting), Formal analysis (supporting)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yan-Qing Lu
National Laboratory of Solid-State Microstructures & Collaborative Innovation Center of Advanced Microstructures & College of Engineering and Applied Sciences, Nanjing University, Nanjing, 210093 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Prof. Dr. Qiang Zhao
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
State Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - review & editing (lead)
Search for more papers by this authorDr. Jiao Liu
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
These authors contributed equally to this work.
Contribution: Conceptualization (equal), Data curation (equal), Visualization (equal), Writing - original draft (equal)
Search for more papers by this authorJun-Jie Wu
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
These authors contributed equally to this work.
Contribution: Conceptualization (equal), Data curation (equal), Visualization (equal)
Search for more papers by this authorDr. Juan Wei
State Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
These authors contributed equally to this work.
Contribution: Conceptualization (equal), Data curation (equal), Visualization (equal)
Search for more papers by this authorZhi-Jun Huang
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Data curation (supporting), Formal analysis (supporting), Visualization (supporting)
Search for more papers by this authorXin-Yu Zhou
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Data curation (supporting), Formal analysis (supporting), Visualization (supporting)
Search for more papers by this authorDr. Jin-Ying Bao
Key Laboratory of Polymer Chemistry and Physics of, Ministry of Education Peking University, Beijing, 100871 P. R. China
Contribution: Data curation (supporting)
Search for more papers by this authorProf. Dr. Ruo-Chen Lan
Institute of Advanced Materials, Jiangxi Normal University, Nanchang, 330022 China
Contribution: Data curation (supporting), Writing - review & editing (supporting)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yun Ma
State Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Prof. Dr. Bing-Xiang Li
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Writing - review & editing (lead)
Search for more papers by this authorProf. Dr. Huai Yang
Key Laboratory of Polymer Chemistry and Physics of, Ministry of Education Peking University, Beijing, 100871 P. R. China
Contribution: Data curation (supporting), Formal analysis (supporting)
Search for more papers by this authorCorresponding Author
Prof. Dr. Yan-Qing Lu
National Laboratory of Solid-State Microstructures & Collaborative Innovation Center of Advanced Microstructures & College of Engineering and Applied Sciences, Nanjing University, Nanjing, 210093 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Prof. Dr. Qiang Zhao
College of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
State Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing, 210023 China
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Funding acquisition (lead), Investigation (lead), Writing - review & editing (lead)
Search for more papers by this authorGraphical Abstract
We propose an effective strategy for achieving circularly polarized organic ultralong room-temperature phosphorescence (CP-OURTP) with a high dissymmetry factor based on a bilayered soft helical superstructure doped with a light-driven molecular motor and room-temperature polymer layer. This enables the significant modulation of reflection across a wide spectral range and the dynamic controlling the dissymmetry factor of CP-OURTP from 1.38 to 0.60.
Abstract
Achieving circularly polarized organic ultralong room-temperature phosphorescence (CP-OURTP) with a high luminescent dissymmetry factor (glum) is crucial for diverse optoelectronic applications. In particular, dynamically controlling the dissymmetry factor of CP-OURTP can profoundly advance these applications, but it is still unprecedented. This study introduces an effective strategy to achieve photoirradiation-driven chirality regulation in a bilayered structure film, which consists of a layer of soft helical superstructure incorporated with a light-driven molecular motor and a layer of room-temperature phosphorescent (RTP) polymer. The prepared bilayered film exhibits CP-OURTP with an emission lifetime of 805 ms and a glum value up to 1.38. Remarkably, the glum value of the resulting CP-OURTP film can be reversibly controlled between 0.6 and 1.38 over 20 cycles by light irradiation, representing the first example of dynamically controlling the glum in CP-OURTP.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the Supporting Information of this article.
Supporting Information
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| anie202319536-sup-0001-misc_information.pdf1.7 MB | Supporting Information |
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