Fcc versus Non-fcc Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence
Dr. Shengli Zhuang
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Lingwen Liao
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Jinyun Yuan
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorDr. Nan Xia
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorYan Zhao
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorProf. Dr. Chengming Wang
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorDr. Zibao Gan
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorDr. Nan Yan
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorLizhong He
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorProf. Dr. Jin Li
Tsinghua University-Peking University Joint Center for Life Sciences, School of Life Sciences, Tsinghua University, Beijing, 100084 P. R. China
Search for more papers by this authorProf. Dr. Haiteng Deng
MOE Key Laboratory of Bioinformatics, School of Life Sciences, Tsinghua University, Beijing, 100084 P. R. China
Search for more papers by this authorDr. Zhaoyong Guan
Center for Multidimensional Carbon Materials, Institute for Basic Science (IBS), Ulsan, 44919 Republic of Korea
Search for more papers by this authorProf. Dr. Jinlong Yang
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Zhikun Wu
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorDr. Shengli Zhuang
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Lingwen Liao
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Jinyun Yuan
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorDr. Nan Xia
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorYan Zhao
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorProf. Dr. Chengming Wang
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorDr. Zibao Gan
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorDr. Nan Yan
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorLizhong He
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorProf. Dr. Jin Li
Tsinghua University-Peking University Joint Center for Life Sciences, School of Life Sciences, Tsinghua University, Beijing, 100084 P. R. China
Search for more papers by this authorProf. Dr. Haiteng Deng
MOE Key Laboratory of Bioinformatics, School of Life Sciences, Tsinghua University, Beijing, 100084 P. R. China
Search for more papers by this authorDr. Zhaoyong Guan
Center for Multidimensional Carbon Materials, Institute for Basic Science (IBS), Ulsan, 44919 Republic of Korea
Search for more papers by this authorProf. Dr. Jinlong Yang
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, Anhui, 230026 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dr. Zhikun Wu
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, 230031 P. R. China
Institute of Physical Science and Information Technology, Anhui University, Hefei, Anhui, 230601 P. R. China
Search for more papers by this authorGraphical Abstract
Cores and effect: A so-called “ion-induction” method gives a unique gold nanocluster with a twist mirror symmetry structure. The as-synthesized nanocluster has the same composition but a different packing of the core kernel atoms (fcc vs. non-fcc) with an existing gold nanocluster Au42(TBBT)26 (TBBT=4-tert-butylbenzenethiolate), and shows photoluminescence that is dependent on the kernel-atom packing.
Abstract
Structural isomerism allows the correlation between structures and properties to be investigated. Unfortunately, the structural isomers of metal nanoparticles are rare and genuine structural isomerism with distinctly different kernel atom packing (e.g., face-centered cubic (fcc) vs. non-fcc) has not been reported until now. Herein we introduce a novel ion-induction method to synthesize a unique gold nanocluster with a twist mirror symmetry structure. The as-synthesized nanocluster has the same composition but different kernel atom packing to an existing gold nanocluster Au42(TBBT)26 (TBBT=4-tert-butylbenzenethiolate). The fcc-structured Au42(TBBT)26 nanocluster shows more enhanced photoluminescence than the non-fcc-structured Au42(TBBT)26 nanocluster, indicating that the fcc-structure is more beneficial for emission than the non-fcc structure. This idea was supported by comparison of the emission intensity of another three pairs of gold nanoclusters with similar compositions and sizes but with different kernel atom packings (fcc vs. non-fcc).
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