“On Water” Surface-initiated Polymerization of Hydrophobic Monomers
Yunjiao Che
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069 Dresden, Germany
Search for more papers by this authorCorresponding Author
Dr. Tao Zhang
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Search for more papers by this authorYunhao Du
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Search for more papers by this authorDr. Ihsan Amin
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Leibniz-Institut für Plasmaforschung und Technologie, Felix-Hausdorff-Straße 2, 17489 Greifswald, Germany
Search for more papers by this authorClaudia Marschelke
Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069 Dresden, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Rainer Jordan
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Search for more papers by this authorYunjiao Che
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069 Dresden, Germany
Search for more papers by this authorCorresponding Author
Dr. Tao Zhang
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Search for more papers by this authorYunhao Du
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Search for more papers by this authorDr. Ihsan Amin
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Leibniz-Institut für Plasmaforschung und Technologie, Felix-Hausdorff-Straße 2, 17489 Greifswald, Germany
Search for more papers by this authorClaudia Marschelke
Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, 01069 Dresden, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Rainer Jordan
Chair of Macromolecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Mommsenstr. 4, 01069 Dresden, Germany
Search for more papers by this authorGraphical Abstract
(B)rush order: “On water” surface-initiated Cu-mediated controlled radical polymerization (“on water” SI-CuCRP) is presented. By using this approach hydrophobic monomers in aqueous reaction medium and in the presence of oxygen are converted to polymer brushes at unparalleled speed and efficiency.
Abstract
We present the “on water” surface-initiated Cu-mediated controlled radical polymerization (“on water” SI-CuCRP) that converts hydrophobic monomers in aqueous reaction medium to polymer brushes at unparalleled speed and efficiency. The method allows the facile conversion of a variety of common monomers under most simple reaction conditions and with minimal monomer amounts to thick and homogeneous polymer brushes. The highly living character of the “on water” SI-CuCRP allowed the preparation of decablock (homo)polymer brushes and opens the pathway to sequentially controlled polymer brushes on solids.
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