Fabrication of Hollow Materials by Fast Pyrolysis of Cellulose Composite Fibers with Heterogeneous Structures
Dr. Yue Dong
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Baoquan Jia
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Feiya Fu
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Heyou Zhang
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorProf. Lina Zhang
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Jinping Zhou
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Yue Dong
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Baoquan Jia
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Feiya Fu
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorDr. Heyou Zhang
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorProf. Lina Zhang
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Jinping Zhou
Department of Chemistry and Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan, 430072 China
Search for more papers by this authorGraphical Abstract
Hollow structural materials were fabricated from cuprammonium cellulose composite filaments by fast pyrolysis. The whole process could be completed within 100 s. The formation mechanism is related to the heterogeneous structure of the fibers and the gradient distribution of the metal oxides in the cellulose matrix.
Abstract
A facile method for the fabrication of inorganic hollow materials from cuprammonium cellulose composite filaments based on fast pyrolysis has been developed. Unlike Ostwald ripening, approaches based on the Kirkendall effect, and other template methods, this process yielded hollow materials within 100 s. The heterogeneous structure of the cellulose composite fibers and the gradient distribution of the metal oxides are the main reasons for the formation of the hollow structure. The diameter, wall thickness, and length of the hollow microfibers could be conveniently controlled. With their perfect morphology, these hollow structural materials have great potential for use in various fields.
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