Visualizing the Dynamics of Temperature- and Solvent-Responsive Soft Crystals
Jiandong Pang
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorDr. Caiping Liu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorDr. Yougui Huang
Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka, 8190395 Japan
Search for more papers by this authorCorresponding Author
Prof. Mingyan Wu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorProf. Feilong Jiang
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorCorresponding Author
Prof. Daqiang Yuan
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorFalu Hu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorDr. Kongzhao Su
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorGuoliang Liu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorProf. Maochun Hong
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorJiandong Pang
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorDr. Caiping Liu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorDr. Yougui Huang
Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka, 8190395 Japan
Search for more papers by this authorCorresponding Author
Prof. Mingyan Wu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorProf. Feilong Jiang
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorCorresponding Author
Prof. Daqiang Yuan
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorFalu Hu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorDr. Kongzhao Su
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorGuoliang Liu
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorProf. Maochun Hong
State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, CAS, Fuzhou, 350002 Fujian, China
Search for more papers by this authorGraphical Abstract
See the shrink: A record high uniaxial positive thermal expansion coefficient of 653.2×10−6 K−1 and large c-axial shrinkage of 32.4 %, is found for metal–organic framework (MOF) temperature- and solvent-responsive soft crystals. The dynamic process can both be visualized by in situ single-crystal X-ray snapshot analyses. The stimuli-responsive mechanism results from rotations and deformations of the organic linkers.
Abstract
We demonstrate that three flexible MOFs termed FJI-H11-R (FJI-H=Hong's group in Fujian Institute of Research on the Structure of Matter, R=Me, Et, iPr) can reversibly respond to temperature and solvents via structural transformations, which can be visualized by in situ single-crystal X-ray snapshot analyses. FJI-H11-R exhibit colossal anisotropic thermal expansion, with a record-high uniaxial positive thermal-expansion coefficient of 653.2×10−6 K−1 observed in FJI-H11-Me. Additionally, large c-axial shrinkage of 32.4 % is also observed during desolvation. The stimuli-responsive mechanism reveals the structural evolutions are related to the rotations and deformations of the organic linkers.
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