Giant Magnetoresistance in the Half-Metallic Double-Perovskite Ferrimagnet Mn2FeReO6
Dr. Man-Rong Li
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Maria Retuerto
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Niels Bohr Institute, University of Copenhagen, 2100 Copenhagen (Denmark)
Search for more papers by this authorZheng Deng
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Peter W. Stephens
Department of Physics & Astronomy, State University of New York, Stony Brook, NY 11794 (USA)
Search for more papers by this authorDr. Mark Croft
Department of Physics & Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Qingzhen Huang
Center for Neutron Research, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899-6102 (USA)
Search for more papers by this authorHui Wu
Center for Neutron Research, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899-6102 (USA)
Search for more papers by this authorXiaoyu Deng
Department of Physics & Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorGabriel Kotliar
Department of Physics & Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Javier Sánchez-Benítez
Departamento de Química Física I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid (Spain)
Search for more papers by this authorDr. Joke Hadermann
EMAT, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp (Belgium)
Search for more papers by this authorDr. David Walker
Lamont-Doherty Earth Observatory, Columbia University, 61 Route 9W, Palisades, NY 10964 (USA)
Search for more papers by this authorCorresponding Author
Prof. Martha Greenblatt
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)Search for more papers by this authorDr. Man-Rong Li
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Maria Retuerto
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Niels Bohr Institute, University of Copenhagen, 2100 Copenhagen (Denmark)
Search for more papers by this authorZheng Deng
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Peter W. Stephens
Department of Physics & Astronomy, State University of New York, Stony Brook, NY 11794 (USA)
Search for more papers by this authorDr. Mark Croft
Department of Physics & Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Qingzhen Huang
Center for Neutron Research, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899-6102 (USA)
Search for more papers by this authorHui Wu
Center for Neutron Research, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899-6102 (USA)
Search for more papers by this authorXiaoyu Deng
Department of Physics & Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorGabriel Kotliar
Department of Physics & Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (USA)
Search for more papers by this authorDr. Javier Sánchez-Benítez
Departamento de Química Física I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid (Spain)
Search for more papers by this authorDr. Joke Hadermann
EMAT, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp (Belgium)
Search for more papers by this authorDr. David Walker
Lamont-Doherty Earth Observatory, Columbia University, 61 Route 9W, Palisades, NY 10964 (USA)
Search for more papers by this authorCorresponding Author
Prof. Martha Greenblatt
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854 (USA)Search for more papers by this authorGraphical Abstract
The first transition-metal-only double perovskite, Mn2+2Fe3+Re5+O6, displays ferrimagnetic ordering up to 520 K and a giant positive magnetoresistance of up to 220 % at 5 K and 8 T. These properties result from the ferrimagnetically coupled Fe and Re sublattice and are affected by a two-to-one magnetic-structure transition of the Mn sublattice when a magnetic field is applied.
Abstract
The first transition-metal-only double perovskite compound, Mn2+2Fe3+Re5+O6, with 17 unpaired d electrons displays ferrimagnetic ordering up to 520 K and a giant positive magnetoresistance of up to 220 % at 5 K and 8 T. These properties result from the ferrimagnetically coupled Fe and Re sublattice and are affected by a two-to-one magnetic-structure transition of the Mn sublattice when a magnetic field is applied. Theoretical calculations indicate that the half-metallic state can be mainly attributed to the spin polarization of the Fe and Re sites.
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