Communication
XeF2/Fluoride Acceptors as Versatile One-Electron Oxidants†
Dr. Helmut Poleschner,
Prof. Dr. Konrad Seppelt,
Corresponding Author
Dr. Helmut Poleschner
Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany)
Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany)===Search for more papers by this authorProf. Dr. Konrad Seppelt
Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany)
Search for more papers by this authorDr. Helmut Poleschner,
Prof. Dr. Konrad Seppelt,
Corresponding Author
Dr. Helmut Poleschner
Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany)
Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany)===Search for more papers by this authorProf. Dr. Konrad Seppelt
Institut für Chemie und Biochemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin (Germany)
Search for more papers by this author†
We thank the Deutsche Forschungsgemeinschaft (Project PO 1503/1) and the Fonds der Chemischen Industrie for the support of this work, and Stefan Ellrodt for the synthesis of (Et3Si+)2 B12Cl122−.
Graphical Abstract
No phlogiston but xenon is released when XeF2/F− acceptors act as new one-electron oxidants. F− acceptors are Lewis acids BF3, B(C6F5)3, and Al{OC(CF3)3}3, and silyl derivatives TfOSiMe3, Tf2NSiMe3, Me3Si+ B(C6F5)4−, and Me3Si+ CHB11Cl11−. The anions BF4−, TfO−, Tf2N−, FB(C6F5)3−, FAl{OC(CF3)3}3−, B(C6F5)4−, or CHB11Cl11− can be introduced into oxidation products of R2E2 (E=S, Se, Te), [FeCp2], [(FeCpS)4], tetrathiafulvalene, thianthrene, and (2,4-Br2C6H3)3N.
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