Observing the Formation and the Reactivity of an Octahedral Iron(V) Nitrido Complex in Real Time†
Dr. Joel Torres-Alacan
Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer
Search for more papers by this authorUjjal Das
Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany)
Search for more papers by this authorProf. Dr. Alexander C. Filippou
Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Peter Vöhringer
Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer
Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer===Search for more papers by this authorDr. Joel Torres-Alacan
Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer
Search for more papers by this authorUjjal Das
Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany)
Search for more papers by this authorProf. Dr. Alexander C. Filippou
Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Peter Vöhringer
Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer
Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Wegelerstrasse 12, 53117 Bonn (Germany) http://www.chemie.uni-bonn.de/pctc/voehringer===Search for more papers by this authorFinancial support by the Deutsche Forschungsgemeinschaft through SFB 813 is gratefully acknowledged
Graphical Abstract
Give me five: Time-resolved Fourier-transform IR spectroscopy is used to time-resolve the formation and the reaction dynamics of a fourfold symmetrical nitrido iron(V) complex (light blue C, red Fe, blue N) in liquid solution under physiological and technologically relevant conditions.
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