Visible-Light Hypervalent Iodide Carboxylate Photo(trifluoro)methylations and Controlled Radical Polymerization of Fluorinated Alkenes†
Corresponding Author
Prof. Alexandru D. Asandei
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)===Search for more papers by this authorOlumide I. Adebolu
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Search for more papers by this authorChristopher P. Simpson
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Search for more papers by this authorJoon-Sung Kim
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Search for more papers by this authorCorresponding Author
Prof. Alexandru D. Asandei
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)===Search for more papers by this authorOlumide I. Adebolu
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Search for more papers by this authorChristopher P. Simpson
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Search for more papers by this authorJoon-Sung Kim
Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA)
Search for more papers by this authorThe University of Connecticut is acknowledged for support.
Graphical Abstract
IFAB-ulous trifluoromethylation: (CX3COO)2IIIIPh (X=F, H) and (CH3COO)3IV(C6H4COO) are introduced as CX3./CX3I precursors for metal-free, visible-light, radical (trifluoro)(iodo)methylations of alkenes, illustrated by their use as photoinitiators for the controlled radical polymerization of vinylidene fluoride with external (I(CF2)6I) and in situ generated (CF3I) iodine chain transfer agents, and for block copolymer synthesis.
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