pH-Switchable Ampholytic Supramolecular Copolymers†
Hendrik Frisch
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
CeNTech, Münster (Germany)
Search for more papers by this authorJan Patrick Unsleber
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
Search for more papers by this authorDavid Lüdeker
Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster (Germany)
Search for more papers by this authorDr. Martin Peterlechner
Institut für Materialphysik, Westfälische Wilhelms-Universität Münster (Germany)
Search for more papers by this authorPriv.-Doz. Dr. Gunther Brunklaus
Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster (Germany)
Search for more papers by this authorDr. Mark Waller
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
Search for more papers by this authorCorresponding Author
Dr. Pol Besenius
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
CeNTech, Münster (Germany)
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com===Search for more papers by this authorHendrik Frisch
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
CeNTech, Münster (Germany)
Search for more papers by this authorJan Patrick Unsleber
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
Search for more papers by this authorDavid Lüdeker
Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster (Germany)
Search for more papers by this authorDr. Martin Peterlechner
Institut für Materialphysik, Westfälische Wilhelms-Universität Münster (Germany)
Search for more papers by this authorPriv.-Doz. Dr. Gunther Brunklaus
Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster (Germany)
Search for more papers by this authorDr. Mark Waller
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
Search for more papers by this authorCorresponding Author
Dr. Pol Besenius
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com
CeNTech, Münster (Germany)
Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Münster (Germany) http://www.besenius-group.com===Search for more papers by this authorWe thank Prof. Dr. Bart Jan Ravoo for critical reading of the manuscript, and acknowledge funding from the “Fonds der Chemischen Industrie” for a doctoral Fellowship (H.F.) and a Liebig Fellowship (P.B.).
Graphical Abstract
β-sheet-encoded anionic and cationic dendritic peptide amphiphiles form supramolecular copolymers when self-assembled in a 1:1 feed ratio of the monomers. These ampholytic materials have been designed for on-off polymerization in response to pH triggers. The cooperative supramolecular self-assembly process is switched on at a physiologically relevant pH value and can be switched off by increasing or decreasing the pH value.
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