Communication

Capping with Multivalent Surfactants for Zeolite Nanocrystal Synthesis^†

Changbum Jo

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

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Jinhwan Jung,

Jinhwan Jung

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

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Hye Sun Shin,

Hye Sun Shin

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

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Jaeheon Kim,

Jaeheon Kim

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

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Prof. Ryong Ryoo,

Corresponding Author

Prof. Ryong Ryoo

[email protected]

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr===Search for more papers by this author

Changbum Jo,

Changbum Jo

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

Search for more papers by this author

Jinhwan Jung,

Jinhwan Jung

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

Search for more papers by this author

Hye Sun Shin,

Hye Sun Shin

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

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Jaeheon Kim,

Jaeheon Kim

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

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Prof. Ryong Ryoo,

Corresponding Author

Prof. Ryong Ryoo

[email protected]

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr

Department of Chemistry, KAIST, Daejeon 305-701 (Republic of Korea)

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science(IBS), Daejeon 305-701 (Republic of Korea) http://rryoo.kaist.ac.kr===Search for more papers by this author

First published: 01 August 2013

https://doi.org/10.1002/anie.201303088

Citations: 95

^†

This work was supported by the Institute for Basic Science in Korea.

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Graphical Abstract

Multiammonium surfactants exhibited a remarkable capping effect for zeolite synthesis in the forms of nanoparticles, nanorods, and nanosponges in cases where common monovalent surfactants failed. A nanorod-shaped mordenite zeolite synthesized in this manner showed significantly enhanced catalytic lifetimes in acid-catalyzed cumene synthesis reactions.

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References

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Volume52, Issue38

September 16, 2013

Pages 10014-10017

Capping with Multivalent Surfactants for Zeolite Nanocrystal Synthesis^†

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Capping with Multivalent Surfactants for Zeolite Nanocrystal Synthesis^†