Morphology Control of Polymer Particles in Ethylene/Carbon Monoxide Copolymerization†
Ji Hae Park
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorKyoung Hwan Oh
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorSung Hun Kim
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorAnish Cyriac
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorJobi Kodiyan Varghese
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorProf. Myung Whan Hwang
Department of Safety Engineering, Incheon University, Incheon 406-772 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Bun Yeoul Lee
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylabSearch for more papers by this authorJi Hae Park
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorKyoung Hwan Oh
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorSung Hun Kim
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorAnish Cyriac
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorJobi Kodiyan Varghese
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorProf. Myung Whan Hwang
Department of Safety Engineering, Incheon University, Incheon 406-772 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Bun Yeoul Lee
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylabSearch for more papers by this authorThis work was supported by Mid-carrier Researcher Program (No. 2011-0000111) and by Priority Research Centers Program (2010-0028294) through NRF of Korea.
Graphical Abstract
Partial to particular particles: The morphology of the polymer particles can be controlled in ethylene/CO copolymerization by pressurizing catalyst-containing 1-octanol droplets dispersed in water. The palladium catalyst should be harnessed with lipophilic long alkyl chains. Polymer particles of 0.5–1.0 mm size (see micrographs) with bulk densities of 0.2–0.3 g mL−1 are produced without reactor fouling.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
| Filename | Description |
|---|---|
| anie_201105270_sm_miscellaneous_information.pdf857.7 KB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aE. Drent, P. H. M. Budzelaar, Chem. Rev. 1996, 96, 663–681;
- 1bE. Drent, J. A. M. Van Broekhoven, M. J. Doyle, J. Organomet. Chem. 1991, 417, 235–251.
- 2
- 2aT. M. J. Anselment, S. I. Vagin, B. Rieger, Dalton Trans. 2008, 4537–4548;
- 2bT. Kageyama, S. Ito, K. Nozaki, Chem. Asian J. 2011, 6, 690–697;
- 2cA. Nakamura, K. Munakata, S. Ito, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki, J. Am. Chem. Soc. 2011, 133, 6761–6779;
- 2dJ. Liu, B. T. Heaton, J. A. Iggo, R. Whyman, Angew. Chem. 2004, 116, 92–96; Angew. Chem. Int. Ed. 2004, 43, 90–94.
- 3J. A. M. van Broekhoven, R. L. Wife (Shell), EP 257663, 1992.
- 4
- 4aA. H. Tullo, Chem. Eng. News 2002, 80, 13–19;
- 4bT. Morita, R. Taniguchi, J. Kato, J. Appl. Polym. Sci. 2004, 94, 446–452.
- 5
- 5aW. Feng, L. D. Sun, Y. W. Zhang, C. H. Yan, Coord. Chem. Rev. 2010, 254, 1038–1053;
- 5bT. L. Kelly, M. O. Wolf, Chem. Soc. Rev. 2010, 39, 1526–1535.
- 6
- 6aR. Arshady, Colloid Polym. Sci. 1992, 270, 717–732;
- 6bB. Brooks, Chem. Eng. Technol. 2010, 33, 1737–1744.
- 7
- 7aL. L. Böhm, Angew. Chem. 2003, 115, 5162–5183;
10.1002/ange.200300580 Google ScholarAngew. Chem. Int. Ed. 2003, 42, 5010–5030;
- 7bB. Y. Lee, J. S. Oh, Macromolecules 2000, 33, 3194–3195;
- 7cG. Fink, B. Steinmetz, J. Zechlin, C. Przybyla, B. Tesche, Chem. Rev. 2000, 100, 1377–1390;
- 7dG. G. Hlatky, Chem. Rev. 2000, 100, 1347–1376.
- 8
- 8aT. Imamoto, T. Oshiki, T. Onozawa, T. Kusumoto, K. Sato, J. Am. Chem. Soc. 1990, 112, 5244–5252;
- 8bW. E. McEwen, B. D. Beaver, Phosphorus Sulfur Relat. Elem. 1985, 24, 259–273.
- 9J. A. van. Doorn, J. J. M. Snel, N. Meijboom, R. L. Wife (Shell), US 4994592, 1991.
- 10T. J. Mooibroek, E. Bouwman, M. Lutz, A. L. Spek, E. Drent, Eur. J. Inorg. Chem. 2010, 298–310.
- 11
- 11aG. Verspui, F. Schanssema, R. A. Sheldon, Angew. Chem. 2000, 112, 825–827;
10.1002/(SICI)1521-3757(20000218)112:4<825::AID-ANGE825>3.0.CO;2-7 Google ScholarAngew. Chem. Int. Ed. 2000, 39, 804–806;10.1002/(SICI)1521-3773(20000218)39:4<804::AID-ANIE804>3.0.CO;2-Q CAS PubMed Web of Science® Google Scholar
- 11bW. P. Mul, H. Dirkzwager, A. A. Broekhuis, H. J. Heeres, A. J. Van der Linden, A. G. Orpen, Inorg. Chim. Acta 2002, 327, 147–159.
- 12O. Ohsawa, K.-H. Lee, B. S. Kim, S. Lee, I.-S. Kim, Polymer 2010, 51, 2007–2012.
- 13B. Mastenbroek, P. J. M. M. de Smedt (Shell), EP 453011, 1991.
