A Luminescent Metal–Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions†
Banglin Chen Prof. Dr.
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Department of Chemistry, The University of Texas–Pan American, Edinburg, TX 78539-2999 (USA), Fax: (+1) 956-384-5006
Search for more papers by this authorLiangbo Wang
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorYunqing Xiao
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorFrank R. Fronczek Dr.
Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803-1804 (USA)
Search for more papers by this authorMing Xue
Department of Chemistry, The University of Texas–Pan American, Edinburg, TX 78539-2999 (USA), Fax: (+1) 956-384-5006
Search for more papers by this authorYuanjing Cui
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorGuodong Qian Prof. Dr.
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorBanglin Chen Prof. Dr.
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Department of Chemistry, The University of Texas–Pan American, Edinburg, TX 78539-2999 (USA), Fax: (+1) 956-384-5006
Search for more papers by this authorLiangbo Wang
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorYunqing Xiao
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorFrank R. Fronczek Dr.
Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803-1804 (USA)
Search for more papers by this authorMing Xue
Department of Chemistry, The University of Texas–Pan American, Edinburg, TX 78539-2999 (USA), Fax: (+1) 956-384-5006
Search for more papers by this authorYuanjing Cui
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorGuodong Qian Prof. Dr.
Department of Materials Science & Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China), Fax: (+86) 571-879-51234
Search for more papers by this authorThis work was supported by an Award CHE 0718281 from the NSF (B.C.), and in part by the Welch Foundation Grant (BG-0017) to the Department of Chemistry at UTPA. The authors gratefully acknowledge the financial support for this work from PCSIRT, the National Natural Science Foundation of China (Nos. 50532030 and 50625206).
Graphical Abstract
It all makes sense: A rationally developed europium metal–organic framework incorporating immobilized Lewis basic pyridyl sites oriented towards the center of one-dimensional channels is a rare example of a luminescent porous MOF. By comparison of the luminescence intensity quenching effects of various incorporated Lewis acidic metal cations, the MOF exhibits sensor capability.
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