Volume 135, Issue 13 e202217581

Zuschrift

New Oxyhalide Solid Electrolytes with High Lithium Ionic Conductivity >10 mS cm⁻¹ for All-Solid-State Batteries

Corresponding Author

Yoshiaki Tanaka

[email protected]

orcid.org/0000-0003-3126-0561

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Koki Ueno,

Koki Ueno

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Keita Mizuno,

Keita Mizuno

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Kaori Takeuchi,

Kaori Takeuchi

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Tetsuya Asano,

Tetsuya Asano

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Akihiro Sakai,

Akihiro Sakai

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Yoshiaki Tanaka,

Corresponding Author

Yoshiaki Tanaka

[email protected]

orcid.org/0000-0003-3126-0561

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Koki Ueno,

Koki Ueno

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Keita Mizuno,

Keita Mizuno

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Kaori Takeuchi,

Kaori Takeuchi

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Tetsuya Asano,

Tetsuya Asano

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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Akihiro Sakai,

Akihiro Sakai

Technology Division, Applied Material Technology Center, Panasonic Holdings Corporation, 1006 Kadoma, Kadoma City, Osaka, 571-8501 Japan

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First published: 06 February 2023

https://doi.org/10.1002/ange.202217581

Citations: 8

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Abstract

All-solid-state batteries (ASSBs) with inorganic solid electrolytes (SEs) have attracted significant interest as next-generation energy storage. Halides such as Li₃YCl₆ are promising candidates for SE because they combine high oxidation stability and deformability. However, the ionic conductivities of halide SEs are not as high as those of other SEs, especially sulfides. Here, we discover new lithium-metal-oxy-halide materials, LiMOCl₄ (M=Nb, Ta). They exhibit extremely high ionic conductivities of 10.4 mS cm⁻¹ for M=Nb and 12.4 mS cm⁻¹ for M=Ta, respectively, even in cold-pressed powder forms at room temperature, which are comparable to or surpass those of organic liquid electrolytes used in lithium-ion batteries. Bulk-type ASSB cells using the oxyhalides as the cathode SE demonstrate an outstanding rate capability with a capacity retention of 80 % at 5 C/0.1 C. We believe that the proposed oxyhalides are promising SE candidates for the practical applications of ASSBs.

Open Research

Data Availability Statement

The data that support the findings of this study are available on request from the corresponding author. The data are not publicly available due to privacy or ethical restrictions.

Supporting Information

References

1J. Janek, W. G. Zeier, Nat. Energy 2016, 1, 16141.
10.1038/nenergy.2016.141
Web of Science® Google Scholar
2A. Manthiram, X. Yu, S. Wang, Nat. Rev. Mater. 2017, 2, 16103–16118.
10.1038/natrevmats.2016.103
CAS Web of Science® Google Scholar
3Y. Kato, S. Hori, T. Saito, K. Suzuki, M. Hirayama, A. Mitsui, M. Yonemura, H. Iba, R. Kanno, Nat. Energy 2016, 1, 16030.
10.1038/nenergy.2016.30
CAS Web of Science® Google Scholar
4
4aF. Ma, E. Zhao, S. Zhu, W. Yan, D. Sun, Y. Jin, C. Nan, Solid State Ionics 2016, 295, 7–12;
10.1016/j.ssi.2016.07.010
CAS Web of Science® Google Scholar
4bZ. Huang, L. Chen, B. Huang, B. Xu, G. Shao, H. Wang, Y. Li, C.-A. Wang, ACS Appl. Mater. Interfaces 2020, 12, 56118–56125.
10.1021/acsami.0c18674
CAS PubMed Web of Science® Google Scholar
5
5aF. Mizuno, A. Hayashi, K. Tadanaga, M. Tatsumisago, Adv. Mater. 2005, 17, 918–921;
10.1002/adma.200401286
CAS Web of Science® Google Scholar
5bN. Kamaya, K. Homma, Y. Yamakawa, M. Hirayama, R. Kanno, M. Yonemura, T. Kamiyama, Y. Kato, S. Hama, K. Kawamoto, A. Mitsui, Nat. Mater. 2011, 10, 682–686;
10.1038/nmat3066
CAS PubMed Web of Science® Google Scholar
5cF. Han, T. Gao, Y. Zhu, K. J. Gaskell, C. Wang, Adv. Mater. 2015, 27, 3473–3483.
10.1002/adma.201500180
CAS PubMed Web of Science® Google Scholar
6S. Kim, H. Oguchi, N. Toyama, T. Sato, S. Takagi, T. Otomo, D. Arunkumar, N. Kuwata, J. Kawamura, S. Orimo, Nat. Commun. 2019, 10, 1081.
10.1038/s41467-019-09061-9
PubMed Web of Science® Google Scholar
7T. Asano, A. Sakai, S. Ouchi, M. Sakaida, A. Miyazaki, A. Hasegawa, Adv. Mater. 2018, 30, 1803075.
10.1002/adma.201803075
PubMed Web of Science® Google Scholar
8X. Li, J. Liang, X. Yang, K. R. Adair, C. Wang, F. Zhao, X. Sun, Energy Environ. Sci. 2020, 13, 1429–1461.
10.1039/C9EE03828K
CAS Web of Science® Google Scholar
9S. Wang, Q. Bai, A. M. Nolan, Y. Liu, S. Gong, Q. Sun, Y. Mo, Angew. Chem. Int. Ed. 2019, 58, 8039–8043;
10.1002/anie.201901938
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2019, 131, 8123–8127.
10.1002/ange.201901938
Web of Science® Google Scholar
10L. Zhou, T. T. Zuo, C. Y. Kwok, S. Y. Kim, A. Assoud, Q. Zhang, J. Janek, L. F. Nazar, Nat. Energy 2022, 7, 83–93.
10.1038/s41560-021-00952-0
CAS Web of Science® Google Scholar
11Y. Wang, W. D. Richards, S. P. Ong, L. J. Miara, J. C. Kim, Y. Mo, G. Ceder, Nat. Mater. 2015, 14, 1026–1031.
10.1038/nmat4369
CAS PubMed Web of Science® Google Scholar
12H. Kageyama, K. Hayashi, K. Maeda, J. P. Attfield, Z. Hiroi, J. M. Rondinelli, K. R. Poeppelmeier, Nat. Commun. 2018, 9, 772.
10.1038/s41467-018-02838-4
PubMed Web of Science® Google Scholar
13L. Pauling, J. Am. Chem. Soc. 1929, 51, 1010.
10.1021/ja01379a006
CAS Web of Science® Google Scholar
14
14aY. Zhao, L. L. Daemen, J. Am. Chem. Soc. 2012, 134, 15042–15047;
10.1021/ja305709z
CAS PubMed Web of Science® Google Scholar
14bM. Braga, J. A. Ferreira, V. Stockhausen, J. Oliveira, A. El-Azab, J. Mater. Chem. A 2014, 2, 5470–5480;
10.1039/C3TA15087A
CAS Web of Science® Google Scholar
14cS. Li, J. Zhu, Y. Wang, J. W. Howard, X. Lü, Y. Li, R. S. Kumar, L. Wang, L. L. Daemen, Y. Zhao, Solid State Ionics 2016, 284, 14–19;
10.1016/j.ssi.2015.11.027
CAS Web of Science® Google Scholar
14dZ. Deng, D. Ni, D. Chen, Y. Bian, S. Li, Z. Wang, Y. Zhao, InfoMat 2021, 4, e12252.
Web of Science® Google Scholar
15G. Hautier, A. Jain, S. P. Ong, B. Kang, C. Moore, R. Doe, G. Ceder, Chem. Mater. 2011, 23, 3495–3508.
10.1021/cm200949v
CAS Web of Science® Google Scholar
16K. Momma, F. Izumi, J. Appl. Crystallogr. 2011, 44, 1272–1276.
10.1107/S0021889811038970
CAS ADS Web of Science® Google Scholar
17A. D. Sendek, Q. Yang, E. D. Cubuk, K.-A. N. Duerloo, Y. Cui, E. J. Reed, Energy Environ. Sci. 2017, 10, 306–320.
10.1039/C6EE02697D
CAS Web of Science® Google Scholar
18T. F. Willems, C. H. Rycroft, M. Kazi, J. C. Meza, M. Haranczyk, Microporous Mesoporous Mater. 2012, 149, 134–141.
10.1016/j.micromeso.2011.08.020
CAS Web of Science® Google Scholar
19M. T. Rodrigues, G. Babu, H. Gullapalli, K. Kalaga, F. N. Sayed, K. Kato, J. Joyner, P. M. Ajayan, Nat. Energy 2017, 2, 17108.
10.1038/nenergy.2017.108
CAS Web of Science® Google Scholar
20
20aX. Li, J. Liang, N. Chen, J. Luo, K. R. Adair, C. Wang, M. N. Banis, T. K. Sham, L. Zhang, Angew. Chem. Int. Ed. 2019, 58, 16427–16432;
10.1002/anie.201909805
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2019, 131, 16579–16584;
10.1002/ange.201909805
Web of Science® Google Scholar
20bJ. Liang, X. Li, S. Wang, K. R. Adair, W. Li, Y. Zhao, C. Wang, Y. Hu, L. Zhang, S. Zhao, S. Lu, H. Huang, R. Li, Y. Mo, X. Sun, J. Am. Chem. Soc. 2020, 142, 7012–7022.
10.1021/jacs.0c00134
CAS PubMed Web of Science® Google Scholar
21P. Adeli, J. D. Bazak, K. H. Park, I. Kochetkov, A. Huq, G. R. Goward, L. F. Nazar, Angew. Chem. Int. Ed. 2019, 58, 8681–8686;
10.1002/anie.201814222
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2019, 131, 8773–8778.
10.1002/ange.201814222
Web of Science® Google Scholar
22P. E. Stallworth, J. J. Fontanella, M. C. Wintersgill, C. D. Scheidler, J. J. Immel, S. G. Greenbaum, A. S. Gozdz, J. Power Sources 1999, 81, 739–747.
10.1016/S0378-7753(99)00144-5
Web of Science® Google Scholar
23Z. Zhu, I. Chu, Z. Deng, S. P. Ong, Chem. Mater. 2015, 27, 8318–832.
10.1021/acs.chemmater.5b03656
CAS Web of Science® Google Scholar
24D. A. Keen, J. Phys. Condens. Matter 2002, 14, R819.
10.1088/0953-8984/14/32/201
CAS Web of Science® Google Scholar
25D. H. S. Tan, E. A. Wu, H. Nguyen, Z. Chen, M. A. Marple, J. M. Doux, X. Wang, H. Yang, A. Banerjee, Y. S. Meng, ACS Energy Lett. 2019, 4, 2418–2427.
10.1021/acsenergylett.9b01693
CAS Web of Science® Google Scholar
26W. Zhang, T. Leichtweiß, S. P. Culver, R. Koerver, D. Das, D. A. Weber, W. G. Zeier, J. Janek, ACS Appl. Mater. Interfaces 2017, 9, 35888–35896.
10.1021/acsami.7b11530
CAS PubMed Web of Science® Google Scholar
27W. D. Richards, L. J. Miara, Y. Wang, J. C. Kim, G. Ceder, Chem. Mater. 2016, 28, 266–273.
10.1021/acs.chemmater.5b04082
CAS Web of Science® Google Scholar

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Volume135, Issue13

March 20, 2023

e202217581

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New Oxyhalide Solid Electrolytes with High Lithium Ionic Conductivity >10 mS cm⁻¹ for All-Solid-State Batteries

Abstract

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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New Oxyhalide Solid Electrolytes with High Lithium Ionic Conductivity >10 mS cm−1 for All-Solid-State Batteries

Abstract

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

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New Oxyhalide Solid Electrolytes with High Lithium Ionic Conductivity >10 mS cm⁻¹ for All-Solid-State Batteries