A Melt-Quenched Luminescent Glass of an Organic–Inorganic Manganese Halide as a Large-Area Scintillator for Radiation Detection
Jian-Bin Luo
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorJun-Hua Wei
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorDr. Zhi-Zhong Zhang
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorZi-Lin He
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dai-Bin Kuang
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorJian-Bin Luo
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorJun-Hua Wei
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorDr. Zhi-Zhong Zhang
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorZi-Lin He
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dai-Bin Kuang
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275 P. R. China
Search for more papers by this authorAbstract
Glass is a group of materials with appealing qualities, including simplicity in fabrication, durability, and high transparency, and they play a crucial role in the optics field. In this paper, a new organic–inorganic metal halide luminescent glass exhibiting >78 % transmittance at 506–800 nm range together with a high photoluminescence quantum yield (PLQY) of 28.5 % is reported through a low-temperature melt-quenching approach of pre-synthesized (HTPP)2MnBr4 (HTPP=hexyltriphenylphosphonium) single crystal. Temperature-dependent X-ray diffraction, polarizing microscopy, and molecular dynamics simulations were combined to investigate the glass-crystal interconversion process, revealing the disordered nature of the glassy state. Benefiting from the transparent nature, (HTPP)2MnBr4 glass yields an outstanding spatial resolution of 10 lp mm−1 for X-ray imaging. The superb optical properties and facility of large-scale fabrication distinguish the organic–inorganic metal halide glass as a highly promising class of materials for optical devices.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the Supporting Information of this article.
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| ange202216504-sup-0001-misc_information.pdf5.2 MB | Supporting Information |
| ange202216504-sup-0001-SI_A22022102A0147-CCDC2214302.cif1.1 MB | Supporting Information |
| ange202216504-sup-0001-SI_Supplementary_Video_1_Glass_sample_melting.mp420.2 MB | Supporting Information |
| ange202216504-sup-0001-SI_Supplementary_Video_2_700K_simulation.mpg8.4 MB | Supporting Information |
| ange202216504-sup-0001-SI_Supplementary_Video_3_1500K_simulation.mpg12 MB | Supporting Information |
| ange202216504-sup-0001-SI_Supplementary_Video_4_2000K_simulation.mpg10.8 MB | Supporting Information |
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