A Lamellar MXene (Ti3C2Tx)/PSS Composite Membrane for Fast and Selective Lithium-Ion Separation
Zong Lu
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
These authors contributed equally to this work.
Search for more papers by this authorYing Wu
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
These authors contributed equally to this work.
Search for more papers by this authorLi Ding
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yanying Wei
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Haihui Wang
Beijing Key Laboratory for Membrane Materials and Engineering, Department of Chemical Engineering, Tsinghua University, 100084 Beijing, China
Search for more papers by this authorZong Lu
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
These authors contributed equally to this work.
Search for more papers by this authorYing Wu
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
These authors contributed equally to this work.
Search for more papers by this authorLi Ding
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yanying Wei
School of Chemistry and Chemical Engineering, South China University of Technology, 510640 Guangzhou, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Haihui Wang
Beijing Key Laboratory for Membrane Materials and Engineering, Department of Chemical Engineering, Tsinghua University, 100084 Beijing, China
Search for more papers by this authorAbstract
A two-dimensional (2D) laminar membrane with Li+ selective transport channels is obtained by stacking MXene nanosheets with the introduction of poly(sodium 4-styrene sulfonate) (PSS) with active sulfonate sites, which exhibits excellent Li+ selectivity from ionic mixture solutions of Na+, K+, and Mg2+. The Li+ permeation rate through the MXene@PSS composite membrane is as high as 0.08 mol m−2 h−1, while the Li+/Mg2+, Li+/Na+, and Li+/K+ selectivities are 28, 15.5, and 12.7, respectively. Combining the simulation and experimental results, we further confirm that the highly selective rapid transport of partially dehydrated Li+ within subnanochannels can be attributed to the precisely controlled interlayer spacing and the relatively weaker ion-terminal (−SO3−) interaction. This study deepens the understanding of ion-selective permeation in confined channels and provides a general membrane design concept.
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