Emissive Metallacycle-Crosslinked Supramolecular Networks with Tunable Crosslinking Densities for Bacterial Imaging and Killing
Dr. Ponmani Jeyakkumar
State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049 P. R. China
Search for more papers by this authorYongping Liang
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorMengying Guo
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorShuai Lu
Department of Chemistry, University of South Florida, Tampa, FL, 33620 USA
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorDr. Donghua Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorProf. Xiaopeng Li
Department of Chemistry, University of South Florida, Tampa, FL, 33620 USA
Search for more papers by this authorProf. Baolin Guo
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorProf. Gang He
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorDr. Dake Chu
Department of Gastroenterology, The First Affiliated Hospital of Xi'an Jiaotong University, Xi'an, 710061 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Mingming Zhang
State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049 P. R. China
Search for more papers by this authorDr. Ponmani Jeyakkumar
State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049 P. R. China
Search for more papers by this authorYongping Liang
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorMengying Guo
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorShuai Lu
Department of Chemistry, University of South Florida, Tampa, FL, 33620 USA
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorDr. Donghua Xu
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 P. R. China
Search for more papers by this authorProf. Xiaopeng Li
Department of Chemistry, University of South Florida, Tampa, FL, 33620 USA
Search for more papers by this authorProf. Baolin Guo
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorProf. Gang He
Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an, 710054 P. R. China
Search for more papers by this authorDr. Dake Chu
Department of Gastroenterology, The First Affiliated Hospital of Xi'an Jiaotong University, Xi'an, 710061 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Mingming Zhang
State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049 P. R. China
Search for more papers by this authorAbstract
The chemical structures and topologies of the crosslinks in supramolecular networks play a crucial role in their properties and functions. Herein, the preparation of a type of poly(N-isopropylacrylamide) (PNIPAAM)-based supramolecular networks crosslinked by emissive hexagonal metallacycles is presented. The topological connections in these networks greatly affect their properties, as evidenced by their differences in absorption, emission, lower critical solution temperature, and modulus along with the variation of crosslinking densities. The integration of PNIPAAM and metallacycles in the networks benefits them improved bioavailability, making them serve as reagents for bacterial imaging and killing. This study provides a strategy to prepare cavity-crosslinked polymer networks for antibacterial applications.
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