An Organic–Inorganic Hybrid Cathode Based on S–Se Dynamic Covalent Bonds
Correction(s) for this article
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Berichtigung: An Organic–Inorganic Hybrid Cathode Based on S–Se Dynamic Covalent Bonds
- Volume 132Issue 13Angewandte Chemie
- pages: 5025-5025
- First Published online: March 6, 2020
Jiawei Zhao
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Yubing Si
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorZixiao Han
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorDr. Junjie Li
Research Technologies, Indiana University, Indianapolis, IN, 46202 USA
Search for more papers by this authorProf. Wei Guo
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yongzhu Fu
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorJiawei Zhao
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Yubing Si
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorZixiao Han
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorDr. Junjie Li
Research Technologies, Indiana University, Indianapolis, IN, 46202 USA
Search for more papers by this authorProf. Wei Guo
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Yongzhu Fu
College of Chemistry, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorAbstract
A diphenyl trisulfide–selenium nanowire (DPTS-Se) organic–inorganic hybrid cathode material is presented for rechargeable lithium batteries. During discharge, three voltage plateaus associated with three lithiation processes are observed. During recharge, the combination of the radicals formed upon delithiation leads to several new phenyl sulfoselenide compounds which are confirmed by HPLC-QTof-MS. The hybrid cathode exhibits superior cycling stability over pristine Se or DPTS as cathode alone. The first discharge shows a capacity of 96.5 % of the theoretical specific capacity and the cell retains 69.2 % of the initial capacity over 250 cycles. The hybrid cathode also shows a high Coulombic efficiency of over 99 % after 250 cycles. This study demonstrates that the combination of organic polysulfide and selenium can not only improve the utilization of active materials but also enhance the cycling performance.
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