Pressure-Induced Multiphoton Excited Fluorochromic Metal–Organic Frameworks for Improving MPEF Properties
Cheng-Xia Chen
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
These authors contributed equally to this work.
Search for more papers by this authorShao-Yun Yin
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
These authors contributed equally to this work.
Search for more papers by this authorZhang-Wen Wei
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorQian-Feng Qiu
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorNeng-Xiu Zhu
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorYa-Nan Fan
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Prof. Mei Pan
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorProf. Cheng-Yong Su
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorCheng-Xia Chen
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
These authors contributed equally to this work.
Search for more papers by this authorShao-Yun Yin
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
These authors contributed equally to this work.
Search for more papers by this authorZhang-Wen Wei
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorQian-Feng Qiu
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorNeng-Xiu Zhu
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorYa-Nan Fan
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorCorresponding Author
Prof. Mei Pan
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorProf. Cheng-Yong Su
MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275 China
Search for more papers by this authorAbstract
In multiphoton excited fluorescence (MPEF), high-energy upconversion emission is obtained from low-energy excitation by absorbance of two or more photons simultaneously. In a pressure-induced fluorochromic process, the emission energy is switched by outer pressure stimuli. Now, five metal–organic frameworks containing the same ligand with simultaneous multiphoton absorption and pressure-induced fluorochromic attributes were studied. One-, two-, and three-photon excited fluorescence (1/2/3PEF) can be achieved in the frameworks, which exhibit pressure-induced blue-to-yellow fluorochromism. The performances are closely dependent with the topologies, flexibilities, and packing states of the frameworks and chromophores therein. The multiphoton upconversion performance can be intensified by pressure-related structural contraction. Over ten-fold increment in the 2PA active cross-section up to 2217 GM is achieved in pressed LIFM-114 compared with the 210 GM for pristine sample at 780 nm.
Conflict of interest
The authors declare no conflict of interest.
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