REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle-Shaped I5O143− Polyiodate Anion
Jin Chen
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100039 P. R. China
Search for more papers by this authorDr. Chun-Li Hu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorDr. Fei-Fei Mao
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100039 P. R. China
Search for more papers by this authorDr. Bing-Ping Yang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorXiao-Han Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jiang-Gao Mao
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorJin Chen
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100039 P. R. China
Search for more papers by this authorDr. Chun-Li Hu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorDr. Fei-Fei Mao
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100039 P. R. China
Search for more papers by this authorDr. Bing-Ping Yang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorXiao-Han Zhang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jiang-Gao Mao
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 P. R. China
Search for more papers by this authorAbstract
The first examples of rare-earth polyiodates, namely, REI5O14 (RE=Y and Gd), have been prepared by hydrothermal reactions of RE2O3 and H5IO6 in H3PO4 (≥85 wt % in H2O), with extremely high yields (>95 %). They crystalize in the polar space group Cm and feature a brand-new semicircle-shaped [I5O14]3− pentameric polyiodate anion composed of two IO3 and three IO4 polyhedra. Remarkably, both compounds exhibit very large second-harmonic generation (SHG) signals (14× and 15×KH2PO4 (KDP) upon 1064 nm laser radiation for Y and Gd compounds, respectively). Our work shows that the hydrothermal reaction in a phosphoric acid medium facilitates the formation of rare-earth polyiodates.
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