Aufsatz
Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten
Dr. Mohand Melaimi,
Dr. Rodolphe Jazzar,
Dr. Michèle Soleilhavoup,
Prof. Dr. Guy Bertrand,
Dr. Mohand Melaimi
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorDr. Rodolphe Jazzar
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorDr. Michèle Soleilhavoup
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Guy Bertrand
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorDr. Mohand Melaimi,
Dr. Rodolphe Jazzar,
Dr. Michèle Soleilhavoup,
Prof. Dr. Guy Bertrand,
Dr. Mohand Melaimi
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorDr. Rodolphe Jazzar
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorDr. Michèle Soleilhavoup
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Guy Bertrand
UCSD-CNRS Joint Research Chemistry Laboratory, UMI 3555, Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, 92093-0358 USA
Search for more papers by this authorAbstract
Ein Kennzeichen der seit 2005 bekannten cyclischen Alkylaminocarbene (CAACs) ist ihre ausgeprägte Nucleophilie (σ-Donor) und zugleich Elektrophile (π-Akzeptor). Diese Eigenschaften ermöglichen die Aktivierung einer Vielzahl kleiner Moleküle und starker Bindungen, die Stabilisierung hochreaktiver dia- und paramagnetischer Spezies der Haupt- und Nebengruppenelemente sowie die Bildung stabiler Bindungen mit Metallen, was zu robusten Katalysatoren führt. Dieser Aufsatz fasst die wichtigsten Ergebnisse vor 2014 kurz zusammen, wobei der Schwerpunkt jedoch auf den Erkenntnissen der vergangenen drei Jahre liegt.
Conflict of interest
Die Autoren erklären, dass keine Interessenskonflikte vorliegen.
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- 125eA. Armstrong, T. Chivers, M. Parvez, R. T. Boere, Angew. Chem. Int. Ed. 2004, 43, 502–505; Angew. Chem. 2004, 116, 508–511.
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- 133Langlebige neutrale und kristalline kationische Antimonradikale wurden kürzlich beschrieben:
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- 137Y. D. Bidal, M. Lesieur, M. Melaimi, F. Nahra, D. B. Cordes, K. S. A. Arachchige, A. M. Z. Slawin, G. Bertrand, C. S. J. Cazin, Adv. Synth. Catal. 2015, 357, 3155–3161.
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- 141bA. S. Romanov, M. Bochmann, Organometallics 2015, 34, 2439–2454;
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- 142V. Lavallo, G. D. Frey, S. Kousar, B. Donnadieu, G. Bertrand, Proc. Natl. Acad. Sci. USA 2007, 104, 13569–13573.
- 143G. D. Frey, B. Donnadieu, M. Soleilhavoup, G. Bertrand, Chem. Asian J. 2011, 6, 402–405.
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- 145Ein monomeres (NHC)CuH wurde vor kurzem in Lösung charakterisiert: E. A. Romero, P. M. Olsen, R. Jazzar, M. Soleilhavoup, M. Gembicky, G. Bertrand, Angew. Chem. Int. Ed. 2017, 56, 4024–4027; Angew. Chem. 2017, 129, 4082–4085.
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- 147Theoretische Studie über (CAAC)2M0-Komplexe:
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- 148bJ. Fang, B. Zhang, Q. Yao, Y. Yang, J. Xie, N. Yan, Coord. Chem. Rev. 2016, 322, 1–29.
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- 150L. Jin, D. S. Weinberger, M. Melaimi, C. E. Moore, A. L. Rheingold, G. Bertrand, Angew. Chem. Int. Ed. 2014, 53, 9059–9063; Angew. Chem. 2014, 126, 9205–9209.
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