ZnAl-Hydrotalcite-Supported Au25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene
Yuan Tan
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorCorresponding Author
Prof. Xiao Yan Liu
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorDr. Leilei Zhang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Aiqin Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorDr. Lin Li
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorXiaoli Pan
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Shu Miao
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Masatake Haruta
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Department of Applied Chemistry, Tokyo Metropolitan University, Hachioji, Tokyo, 192-0397 Japan
Search for more papers by this authorDr. Haisheng Wei
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorHua Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Fangjun Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Xiaodong Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorCorresponding Author
Prof. Tao Zhang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorYuan Tan
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
University of Chinese Academy of Sciences, Beijing, 100049 China
Search for more papers by this authorCorresponding Author
Prof. Xiao Yan Liu
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorDr. Leilei Zhang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Aiqin Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorDr. Lin Li
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorXiaoli Pan
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Shu Miao
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Masatake Haruta
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Department of Applied Chemistry, Tokyo Metropolitan University, Hachioji, Tokyo, 192-0397 Japan
Search for more papers by this authorDr. Haisheng Wei
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorHua Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Fangjun Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorProf. Xiaodong Wang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorCorresponding Author
Prof. Tao Zhang
State Key Laboratory of Catalysis, iChEM, Gold Catalysis Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023 China
Search for more papers by this authorAbstract
Chemoselective hydrogenation of 3-nitrostyrene to 3-vinylaniline is quite challenging because of competitive activation of the vinyl group and the nitro group over most supported precious-metal catalysts. A precatalyst comprised of thiolated Au25 nanoclusters supported on ZnAl-hydrotalcite yielded gold catalysts of a well-controlled size (ca. 2.0 nm)—even after calcination at 500 °C. The catalyst showed excellent selectivity (>98 %) with respect to 3-vinylaniline, and complete conversion of 3-nitrostyrene over broad reaction duration and temperature windows. This result is unprecedented for gold catalysts. In contrast to traditional catalysts, the gold catalyst is inert with respect to the vinyl group and is only active with regard to the nitro group, as demonstrated by the results of the control experiments and attenuated total reflection infrared spectra. The findings may extend to design of gold catalysts with excellent chemoselectivity for use in the synthesis of fine chemicals.
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