Halogen-Bond-Templated [2+2] Photodimerization in the Solid State: Directed Synthesis and Rare Self-Inclusion of a Halogenated Product
Michael A. Sinnwell
Department of Chemistry, University of Iowa, E555 Chemistry Building, Iowa City, IA, 52242 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Leonard R. MacGillivray
Department of Chemistry, University of Iowa, E555 Chemistry Building, Iowa City, IA, 52242 USA
Search for more papers by this authorMichael A. Sinnwell
Department of Chemistry, University of Iowa, E555 Chemistry Building, Iowa City, IA, 52242 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Leonard R. MacGillivray
Department of Chemistry, University of Iowa, E555 Chemistry Building, Iowa City, IA, 52242 USA
Search for more papers by this authorAbstract
A ditopic halogen-bond acceptor organizes a diiodooctafluorostilbene for a [2+2] photodimerization reaction to take place between two stilbene molecules in the solid state. The resultant cyclobutane product is functionalized with halogen atoms and undergoes self-assembly to form a channel-type host–guest compound that exhibits a very rare form of self-inclusion.
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